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Vilka [71]
3 years ago
9

A mouse is placed in a sealed chamber with air at 769.0 torr. This chamber is equipped with enough solid KOH to absorb any CO2 a

nd H2O produced by the mouse. The gas volume in this chamber is measured to be exactly 2.20 L, the temperature is held constant at 292 K. After two hours the pressure inside the bottle falls to 717.1 torr. What mass of oxygen has the mouse consumed?
Chemistry
1 answer:
svlad2 [7]3 years ago
5 0

<u>Answer:</u> The amount of oxygen gas consumed by mouse is 0.202 grams.

<u>Explanation:</u>

We are given:

Initial pressure of air = 769.0 torr

Final pressure of air = 717.1 torr

Pressure of oxygen = Pressure decreased = Initial pressure - Final pressure = (769.0 - 717.1) torr = 51.9 torr

To calculate the amount of oxygen gas consumed, we use the equation given by ideal gas which follows:

PV=nRT

where,

P = pressure of the gas = 51.9 torr

V = Volume of the gas = 2.20 L

T = Temperature of the gas = 292 K

R = Gas constant = 62.364\text{ L. Torr }mol^{-1}K^{-1}

n = number of moles of oxygen gas = ?

Putting values in above equation, we get:

51.9torr\times 2.20L=n\times 62.364\text{ L. Torr }mol^{-1}K^{-1}\times 292K\\\\n=\frac{51.9\times 2.20}{62.364\times 292}=0.0063mol

To calculate the mass from given number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}

Moles of oxygen gas = 0.0063 moles

Molar mass of oxygen gas = 32 g/mol

Putting values in above equation, we get:

0.0063mol=\frac{\text{Mass of oxygen gas}}{32g/mol}\\\\\text{Mass of oxygen gas}=(0.0063mol\times 32g/mol)=0.202g

Hence, the amount of oxygen gas consumed by mouse is 0.202 grams.

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A 0.00143 M  concentration of MnO4^- is not a reasonable solution .

<h3>Number of moles of carbonate</h3>

The ions left in solution are Na^+ and NO3^-

Number of moles of calcium nitrate  = 100/1000 L × 1 = 0.1 moles

Since;

1 mole of sodium carbonate reacts with 1 mole of calcium nitrate  then 0.1 moles of sodium carbonate were used.

<h3>Conductivity of filtrate</h3>

The claim of the student that the concentration of sodium carbonate is too low is wrong because the value was calculated from concentration  and volume of calcium nitrate  and not using the precipitate. If the filtrate is tested for conductivity, it will be found to conduct electricity because it contains sodium and NO3 ions.

2) In the reaction as shown, the MnO4^- ion was reduced.

The initial volume is 3.4 mL while the final volume is 29.6 mL.

Number of moles of MnO4^- ion = (29.6 mL - 3.4 mL)/1000 × 0.0235 M = 0.0006157 moles

<h3>The calculations are performed as follows</h3>

  • If 2 moles of MnO4^- reacted with 5 moles of acid

0.0006157 moles of MnO4^- reacted with  0.0006157 moles ×  5 moles/ 2 moles

= 0.0015 moles

  • In this case, number of moles of acid = 0.139 g/90 g/mol = 0.0015 moles

Number of moles of MnO4^-  = 0.00143 M × (29.6 mL - 3.4 mL)/1000

= 0.000037 moles

  • If 2 moles of MnO4^- reacts with 5 moles of acid

0.000037 moles of MnO4^- reacts with 0.000037 moles × 5 moles/ 2 moles

= 0.000093 moles

  • Hence, this is not a reasonable amount of solution.

Learn more about MnO4^- : brainly.com/question/10887629

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Be sure to answer all parts. The equilibrium constant (Kp) for the reaction below is 4.40 at 2000. K. H2(g) + CO2(g) ⇌ H2O(g) +
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<u>Answer:</u>

<u>For 1:</u> The value of \Delta G for the chemical equation is -24.636 kJ/mol

<u>For 2:</u> The value of \Delta G for the chemical equation is -20.925 kJ/mol

<u>Explanation:</u>

For the given chemical equation:

H_2(g)+CO_2(g)\rightleftharpoons H_2O(g)+CO(g)

  • <u>For 1:</u>

To calculate the \Delta G for given value of equilibrium constant, we use the relation:

\Delta G=-RT\ln K_p      .....(1)

where,

\Delta G = ? kJ/mol

R = Gas constant = 8.314J/K mol

T = temperature = 2000 K

K_p = equilibrium constant in terms of partial pressure = 4.40

Putting values in above equation, we get:

\Delta G=-(8.314J/Kmol)\times 2000K\times \ln (4.40)\\\\\Delta G=-24636.12J/mol

Converting this into kilo joules, we use the conversion factor:

1 kJ = 1000 J

So, -24636.12 J/mol = -24.636 kJ/mol

Hence, the value of \Delta G for the chemical equation is -24.636 kJ/mol

  • <u>For 2:</u>

The expression of K_p for the given chemical equation is:

K_p=\frac{p_{CO}p_{H_2O}}{p_{H_2}p_{CO_2}}

We are given:

p_{CO}=1.18atm\\p_{H_2O}=0.66atm\\p_{CO_2}=0.82atm\\p_{H_2}=0.27atm

Putting values in above equation, we get:

K_p=\frac{1.18\times 0.66}{0.27\times 0.82}\\\\K_p=3.52

Now, calculating the value of \Delta G by using equation 1:

R = Gas constant = 8.314J/K mol

T = temperature = 2000 K

K_p = equilibrium constant in terms of partial pressure = 3.52

Putting values in equation 1, we get:

\Delta G=-(8.314J/Kmol)\times 2000K\times \ln (3.52)\\\\\Delta G=-20925.68J/mol

Converting this into kilo joules, we use the conversion factor:

1 kJ = 1000 J

So, -20925.68 J/mol = -20.925 kJ/mol

Hence, the value of \Delta G for the chemical equation is -20.925 kJ/mol

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