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marta [7]
3 years ago
12

A 51.9 g sample of quartz is put into a calorimeter (see sketch at right) that contains 300.0 g of water. The quartz sample star

ts off at 97.8 °C and the temperature of the water starts off at 17.0 °C. When the temperature of the water stops changing it's 19.3 °C. The pressure remains constant at 1 atm. insulated container water sample Calculate the specific heat capacity of quartz according to this experiment. Be sure your answer is rounded to 2 significant digits. a calorimeter g °C.
Chemistry
1 answer:
Trava [24]3 years ago
5 0

Answer:

The specific heat capacity of quartz is 0.71 J/g°C.

Explanation:

Heat lost by quartz will be equal to heat gained by the water

-Q_1=Q_2

Mass of quartz= m_1=51.9 g

Specific heat capacity of quartz= c_1=?

Initial temperature of the quartz= T_1=97.8^oC

Final temperature = T_2=T  = 19.3^oC

Q_1=m_1c_1\times (T-T_1)

Mass of water=m_2=300.0 g

Specific heat capacity of water= c_2=4.18 J/g^oC

Initial temperature of the water = T_3=17.0 ^oC

Final temperature of water = T_2=T=19.3^oC

Q_2=m_2c_2\times (T-T_3)

-Q_1=Q_2

-(m_1c_1\times (T-T_1))=m_2c_2\times (T-T_3)

On substituting all values:

-(51.9 gc_1\times (19.3^oC-97.8^oC))=300.0 g\times 4.18 J/g^oC\times (19.3^oC-170^oC)

we get:

c_1 =0.7079 J/g^oC\approx 0.71 J/g^oC

The specific heat capacity of quartz is 0.71 J/g°C.

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Suppose a 2.95 g of potassium iodide is dissolved in 350. mL of a 62.0 m M aqueous solution of silver nitrate. Calculate the fin
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Answer : The final molarity of iodide anion in the solution is 0.0508 M.

Explanation :

First we have to calculate the moles of KI and AgNO_3.

\text{Moles of }KI=\frac{\text{Mass of }KI}{\text{Molar mass of }KI}

Molar mass of KI = 166 g/mole

\text{Moles of }KI=\frac{2.95g}{166g/mole}=0.0178mole

and,

\text{Moles of }AgNO_3=\text{Concentration of }AgNO_3\times \text{Volume of solution}=0.0620M\times 0.350L=0.0217mole

Now we have to calculate the limiting and excess reagent.

The given chemical reaction is:

KI+AgNO_3\rightarrow KNO_3+AgI

From the balanced reaction we conclude that

As, 1 mole of KI react with 1 mole of AgNO_3

So, 0.0178 mole of KI react with 0.0178 mole of AgNO_3

From this we conclude that, AgNO_3 is an excess reagent because the given moles are greater than the required moles and KI is a limiting reagent and it limits the formation of product.

Now we have to calculate the moles of AgI

From the reaction, we conclude that

As, 1 mole of KI react to give 1 mole of AgI

So, 0.0178 moles of KI react to give 0.0178 moles of AgI

Thus,

Moles of AgI = Moles of I^- anion = Moles of Ag^+ cation = 0.0178 moles

Now we have to calculate the molarity of iodide anion in the solution.

\text{Concentration of }AgNO_3=\frac{\text{Moles of }AgNO_3}{\text{Volume of solution}}

\text{Concentration of }AgNO_3=\frac{0.0178mol}{0.350L}=0.0508M

Therefore, the final molarity of iodide anion in the solution is 0.0508 M.

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