Answer:
The percentage (by mass) of KBr in the original mixture was 33.1%.
Explanation:
The mixture of KCl and KBr has a mass of 3.595g, thus the sum of the moles of KCl (<em>x</em>) multiplied by it molar mass (74.5g/mol) and the moles of KBr (<em>y</em>) multiplied by it molar mass (119g/mol) is the total mass of the mixture:

Also, after the conversion of KBr into KCl, the total mass of 3.129 g is only from KCl moles, hence

But the 0.042 moles came from the originals KCl and KBr moles, thus

Now it is possible to propose a system of equations:


Solving the system of equations,

0.010 moles of KBr multiplied it molar mass is

Therefore, the percentage (by mass) of KBr in the original mixture was:
%
The partial pressure of hydrogen is 0.31 atm
calculation
find the number of hydrogen moles the container, that is
25/100 x 6.4 =1.6 moles of hydrogen
find the partial pressure for hydrogen in 1.6 moles
that is 6.4 moles= 1.24 atm
1.6 moles= ?
by cross multiplication
1.6moles x1.24 atm/ 6.4 moles= 0.31 atm
Answer: option A. 350 K and 0.30 atm
Explanation: a gas behaves as an ideal gas at higher temperature and low pressure
Explanation:
The reaction equation will be as follows.

Hence, the expression for
is as follows.
![K_{a} = \frac{[H_{2}SO^{-}_{4}][H^{+}]}{[H_{3}AsO_{4}]}](https://tex.z-dn.net/?f=K_%7Ba%7D%20%3D%20%5Cfrac%7B%5BH_%7B2%7DSO%5E%7B-%7D_%7B4%7D%5D%5BH%5E%7B%2B%7D%5D%7D%7B%5BH_%7B3%7DAsO_%7B4%7D%5D%7D)
Let us assume that the concentration of both
and
is x.

x = 0.01118034
This means that the concentration of
is 0.01118034.
Since, we know that the relation between pH and concentration of hydrogen ions is as follows.
pH = ![-log [H^{+}]](https://tex.z-dn.net/?f=-log%20%5BH%5E%7B%2B%7D%5D)
= 
= 1.958
Thus, we can conclude that the pH of a 0.500 M solution of arsenic acid is 1.958.