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Black_prince [1.1K]
4 years ago
7

What is the coefficient of silver in the final, balanced equation for this reaction?

Chemistry
1 answer:
vekshin14 years ago
8 0

This is an incomplete question, the complete question is attached below.

Answer : The coefficient of silver in the final, balanced equation for this reaction is, 3

Explanation :

Redox reaction or Oxidation-reduction reaction : It is defined as the reaction in which the oxidation and reduction reaction takes place simultaneously.

Oxidation reaction : It is defined as the reaction in which a substance looses its electrons. In this, oxidation state of an element increases. Or we can say that in oxidation, the loss of electrons takes place.

Reduction reaction : It is defined as the reaction in which a substance gains electrons. In this, oxidation state of an element decreases. Or we can say that in reduction, the gain of electrons takes place.

The given redox reaction is,

Ag^+(aq)+Al(s)\rightarrow Ag(s)+Al^{3+}(aq)

The oxidation-reduction half reaction will be :

Oxidation : Al\rightarrow Al^{3+}+3e^-

Reduction : Ag^{+}+1e^-\rightarrow Ag

In order to balance the electrons, we multiply the reduction reaction by 3 and then added both equation, we get the balanced redox reaction.

The balanced redox reaction will be,

3Ag^+(aq)+Al(s)\rightarrow 3Ag(s)+Al^{3+}(aq)

From the balanced redox reaction we conclude that, the coefficient of silver in the final balanced equation for this reaction is 3.

Hence, the correct option is 3.

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8. Select the lattice energy for rubidium chloride from the following data (in kJ/mol]
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Option C

Explanation:

The chemical reactions which are involved while solving this problem is there in the file attached and each chemical reaction is represented by a certain equation number

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Equation 1 represents the change in enthalpy for formation of RbCl

Equation 2 represents the sublimation reaction of rubidium

Equation 3 represents the ionization enthalpy of rubidium

Equation 4 represents the enthalpy of atomization of chlorine which means it describes the bond enthalpy of Cl2 molecule

Equation 5 represents the electron affinity of chlorine

To find the lattice energy for RbCl we have to use all the equations from 1 to 5 so that at last we get the equation 6

We have to perform operations such as

Equation 1 - equation 2 - equation 3 - equation 4 - equation 5

By performing these operations the intermediate compounds gets cancelled and at last we get equation 6

So Equation 1 ≡  ΔH_{f} = -431 kJ/mol

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Equation 4 ≡ BE(Cl2) = 226  kJ/mol

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Value corresponding to the equation 6 will be the value of lattice energy of RbCl and the value is -695·3 kJ/mol

∴ Lattice energy for rubidium chloride is approximately -695 kJ/mol

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Whats the voltage of CuCl2 + Zn -&gt; ZnCl2 + Cu
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Answer:

Approximately 1.10\; {\rm V} under standard conditions.

Explanation:

Equation for the overall reaction:

{\rm CuCl_{2}}\, (aq) + {\rm Zn}\, (s) \to {\rm ZnCl_{2}} \, (aq) + {\rm Cu}\, (s).

Write down the ionic equation for this reaction:

\begin{aligned}& {\rm Cu^{2+}}\, (aq) + 2\; {\rm Cl^{-}}\, (aq) + {\rm Zn}\, (s)\\ & \to {\rm Zn^{2+}} \, (aq) + 2\; {\rm Cl^{-}}\, (aq) + {\rm Cu}\, (s)\end{aligned}.

The net ionic equation for this reaction would be:

{\rm Cu^{2+}}\, (aq) + {\rm Zn}\, (s) \to {\rm Zn^{2+}}\, (aq) + {\rm Cu}\, (s).

In this reaction:

  • Zinc loses electrons and was oxidized (at the anode): {\rm Zn}\, (s) \to {\rm Zn^{2+}}\, (aq) + 2\, {\rm e^{-}}.
  • Copper gains electrons and was reduced (at the cathode): {\rm Cu^{2+}}\, (aq) + 2\, {\rm e^{-}} \to {\rm Cu} \, (s).

Look up the standard potentials for each half-reaction on a table of standard reduction potentials.

Notice that {\rm Zn}\, (s) \to {\rm Zn^{2+}}\, (aq) + 2\, {\rm e^{-}} is oxidation and is likely not on the table of standard reduction potentials. However, the reverse reaction, {\rm Zn^{2+}}\, (aq) + 2\, {\rm e^{-}} \to {\rm Zn}\, (s), is reduction and is likely on the table.

  • E(\text{anode}) = -0.7618\; {\rm V} for {\rm Zn^{2+}}\, (aq) + 2\, {\rm e^{-}} \to {\rm Zn}\, (s), and
  • E(\text{cathode}) = 0.3419\; {\rm V} for {\rm Cu^{2+}}\, (aq) + 2\, {\rm e^{-}} \to {\rm Cu} \, (s).

The reduction potential of {\rm Zn}\, (s) \to {\rm Zn^{2+}}\, (aq) + 2\, {\rm e^{-}} would be -E(\text{anode}) = -(-0.7618\; {\rm V}) = 0.7618\; {\rm V}, the opposite of the reverse reaction {\rm Zn^{2+}}\, (aq) + 2\, {\rm e^{-}} \to {\rm Zn}\, (s).

The standard potential of the overall reaction would be the sum of the standard potentials of the two half-reactions:

\begin{aligned} E^{\circ} &= E^{\circ}(\text{cathode}) + (-E^{\circ}(\text{anode})) \\ &= 0.3419 - (-0.7618\; {\rm V}) \\ &\approx 1.10\; {\rm V}\end{aligned}.

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2 years ago
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