Radio waves are primarily used to

The information below describes a redox reaction.

Rashid [163]

Answer:

Al°(s) + 3Ag⁺(aq) => Al⁺³(aq) + 3Ag(s)

Explanation:

Oxidation: Al°(s) => Al⁺³(aq) + 3e⁻

Reduction: 3Ag⁺(aq) + 3e⁻ => 3Ag°(s)

_________________________________________

Net Rxn: Al°(s) + 3Ag⁺(aq) => Al⁺³(aq) + 3Ag(s)

One mole of neutral aluminum atoms (Al°(s)) undergo oxidation delivering 3 moles of electrons to 3 moles silver ions (3Ag⁺³(aq)) that are reduced to 3 moles of neutral silver atoms (3Ag°(s)) in basic standard state 25°C; 1atm.

7 0

3 years ago

A solution is prepared by dissolving 10.8 g ammonium sulfate in enough water to make 100.0 mL of stock solution. A 10.00 mL samp

kari74 [83]

Answer:NH

+

4

:

0.272

M

SO

2

−

4

:

0.136

M

Explanation:

We can solve this problem using some molarity calculations:

molarity

=

mol solute

L soln

We should convert the given mass of

(NH

4

)

2

SO

4

to moles using its molar mass (calculated to be

132.14

g/mol

):

10.8

g (NH

4

)

2

SO

4

⎛

⎝

1

l

mol (NH

4

)

2

SO

4

132.14

g (NH

4

)

2

SO

4

⎞

⎠

=

0.0817

mol (NH

4

)

2

SO

4

This is the quantity present in

100

mL soln

, so let's calculate the molarity of the solution (converting volume to liters):

molarity

=

0.0817

l

mol (NH

4

)

2

SO

4

0.100

l

L soln

=

0.817

M

10

mL

of this solution is added to

50

mL H

2

O

, which makes a

60

-

mL

total solution.

We can now use the dilution equation

M

1

V

1

=

M

2

V

2

to find the molality of the new,

60

-

mL

solution:

(

0.0817

M

)

(

10

l

mL

)

=

(

M

2

)

(

60

l

mL

)

M

2

=

(

0.817

M

)

(

10

mL

)

60

mL

=

0.136

M

This means that there are

0.136

moles of

(NH

4

)

2

SO

4

per liter of solution.

Let's recognize that

1

mol (NH

4

)

2

SO

4

contains

2

mol NH

+

4

1

mol SO

2

−

4

The concentrations of each ion is thus

(

2

)

(

0.136

M

)

=

0.272

M

NH

+

4

(

1

)

(

0.136

M

)

=

0.136

M

SO

2

−

4

Explanation:

7 0

3 years ago

Consider the titration of a 20.0-mL sample of 0.105 M HC2H3O2 with 0.125 M NaOH. Determine each quantity. a. the initial pH b. t

Oksi-84 [34.3K]

Answer:

Explanation:

Given that:

Concentration of $HC_2H_3O_2 \ (M_1)$ = 0.105 M

Volume of $HC_2H_3O_2 \ (V_1)$ = 20.0 mL

Concentration of $NaOH (M_2)$ = 0.125 M

The chemical reaction can be expressed as:

$HC_2H_3O_2_{(aq)} + NaOH _{(aq)} \to NaC_2H_3O_2_{(aq)} + H_2O_{(l)}$

Using the ICE Table to determine the equilibrium concentrations.

$HC_2 H_3 O_2 _{(aq)} + H_2O _{(l) } \to C_2 H_3O_2^- _{(aq)} + H_3O^+_{ (aq)}$

I 0.105 0 0

C -x +x +x

E 0.105 - x x x

$K_a = \dfrac{[C_2H_5O^-_2][H_3O^+]}{[HC_2H_3O_2]}$

$K_a = \dfrac{(x)(x)}{(0.105-x)}$

Recall that the ka for $HC_2H_3O_2= 1.8 \times 10^{-5}$

Then;

$1.8 \times 10^{-5} = \dfrac{(x)(x)}{(0.105 -x)}$

$1.8 \times 10^{-5} = \dfrac{x^2}{(0.105 -x)}$

By solving the above mathematical expression;

x = 0.00137 M

$H_3O^+ = x = 0.00137 \ M \\ \\ pH = - log [H_3O^+] \\ \\ pH = - log ( 0.00137 )$

pH = 2.86

Hence, the initial pH = 2.86

b) To determine the volume of the added base needed to reach the equivalence point by using the formula:

$M_1 V_1 = M_2 V_2$

$V_2= \dfrac{M_1V_1}{M_2}$

$V_2= \dfrac{0.105 \ M \times 20.0 \ mL }{0.125 \ M}$

$V_2 = 16.8 mL$

Thus, the volume of the added base needed to reach the equivalence point = 16.8 mL

c) when pH of 5.0 mL of the base is added.

The Initial moles of $HC_2H_3O_2 =$ molarity × volume

$= 0.105 \ M \times 20.0 \times 10^{-3} \ L$

$= 2.1 \times 10^{-3}$

number of moles of 5.0 NaOH = molarity × volume

number of moles of 5.0 NaOH = $0.625 \times 10^{-3}$

After reacting with 5.0 mL NaOH, the number of moles is as follows:

$HC_2 H_3 O_2 _{(aq)} + NaOH _{(aq)} \to NaC_2H_3O_2_{(aq)} + H_2O{ (l)}$

Initial moles $2.1*10^{-3}$ $0.625 * 10^{-3}$ 0 0

F(moles) $(2.1*10^{-3} - 0.625 \times 10^{-3})$ 0 $0.625 \times 10^{-3}$ $0.625 \times 10^{-3}$

The pH of the solution is then calculated as follows:

$pH = pKa + log \dfrac{[base]} {[acid]}$

Recall that:

pKa for $HC_2H_3O_2=4.74$

Then; we replace the concentration with the number of moles since the volume of acid and base are equal

∴

$pH = 4.74 + log \dfrac{0.625 \times 10^{-3}}{1.475 \times 10^{-3}}$

pH = 4.37

Thus, the pH of the solution after the addition of 5.0 mL of NaOH = 4.37

d)

We need to understand that the pH at 1/2 of the equivalence point is equal to the concentration of the base and the acid.

Therefore;

pH = pKa = 4.74

e) pH at the equivalence point.

Here, the pH of the solution is the result of the reaction in the $(C_2H_3O^-_2)$ with $H_2O$

The total volume(V) of the solution = V(acid) + V(of the base added to reach equivalence point)

The total volume(V) of the solution = 20.0 mL + 16.8 mL

The total volume(V) of the solution = 36.8 mL

Concentration of $(C_2H_3O^-_2)$ = moles/volume

= $\dfrac{2.1 \times 10^{-3} \ moles}{0.0368 \ L}$

= 0.0571 M

Now, using the ICE table to determine the concentration of $H_3O^+$ ;

$C_2H_5O^-_2 _{(aq)} + H_2O_{(l)} \to HC_2H_3O_2_{(aq)} + OH^-_{(aq)}$

I 0.0571 0 0

C -x +x +x

E 0.0571 - x x x

Recall that the Ka for $HC_2H_3O_2$ = $1.8 \times 10^{-5}$

$K_b = \dfrac{K_w}{K_a} = \dfrac{1.0\times 10^{-14}}{1.8 \times 10^{-5} } \\ \\ K_b = 5.6 \times 10^{-10}$

$k_b = \dfrac{[ HC_2H_3O_2] [OH^-]}{[C_2H_3O^-_2]}$

$5.6 \times 10^{-10} = \dfrac{x *x }{0.0571 -x}$

$x = [OH^-] = 5.6 \times 10^{-6} \ M$

$[H_3O^+] = \dfrac{1.0 \times 10^{-14} }{5.6 \times 10^{-6} }$

$[H_3O^+] =1.77 \times 10^{-9}$

$pH =-log [H_3O^+] \\ \\ pH =-log (1.77 \times 10^{-9}) \\ \\ \mathbf{pH = 8.75 }$

Hence, the pH of the solution at equivalence point = 8.75

f) The pH after 5.09 mL base is added beyond (E) point.

$HC_2 H_3 O_2 _{(aq)} + NaOH _{(aq)} \to NaC_2H_3O_2_{(aq)} + H_2O{ (l)}$

Before 0.0021 0.002725 0

After 0 0.000625 0.0021

$[OH^-] = \dfrac{0.000625 \ moles}{(0.02 + 0.0218 ) \ L}$

$[OH^-] = \dfrac{0.000625 \ moles}{0.0418 \ L}$

$[OH^-] = 0.0149 \ M$

From above; we can determine the concentration of $H_3O^+$ by using the following method:

$[H_3O^+] = \dfrac{1.0 \times 10^{-14} }{0.0149}$

$[H_3O^+] = 6.7 \times 10^{-13}$

$pH = - log [H_3O^+]$

$pH = -log (6.7 \times 10^{-13} )$

pH = 12.17

Finally, the pH of the solution after adding 5.0 mL of NaOH beyond (E) point = 12.17

3 0

3 years ago

According to the _____ hypothesis the solar system formed from a cloud of dust and gas

telo118 [61]

Isn't is the big bang theory

4 0

4 years ago

Read 2 more answers

Why is it important that organisms reproduce in a variety of ways?

hjlf

Hello, this is what I found, Hope it helped

A variety of different ways to reproduce permits a diverse range of organisms to survive a variety of environmental changes.

5 0

3 years ago

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