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Empirical formula is calculated as follows
calculate the moles of each element, that is % composition/ molar mass
molar masses ( Si= 28.09g/mol , Cl= 35.5 g/mol, I=126.9 g/mol)
moles of silicon = 7.962/28.09g/mol= 0.283 moles
moles of chlorine = 20.10 / 35.5g/mol = 0.566 moles
moles of iodine= 71.94 / 126.9 g/mol= 0.567 moles
divide each mole with smallest mole (0.283)
that is silicon = 0.283/0.283= 1 mole
chlorine = 0.566/0.283= 2 mole
Iodine= o.567/0.283= 2 moles
empirical formula is therefore= SiCl2I2
Answer:
Water will boil at
.
Explanation:
According to clausius-clapeyron equation for liquid-vapor equilibrium:
![ln(\frac{P_{2}}{P_{1}})=\frac{-\Delta H_{vap}^{0}}{R}[\frac{1}{T_{2}}-\frac{1}{T_{1}}]](https://tex.z-dn.net/?f=ln%28%5Cfrac%7BP_%7B2%7D%7D%7BP_%7B1%7D%7D%29%3D%5Cfrac%7B-%5CDelta%20H_%7Bvap%7D%5E%7B0%7D%7D%7BR%7D%5B%5Cfrac%7B1%7D%7BT_%7B2%7D%7D-%5Cfrac%7B1%7D%7BT_%7B1%7D%7D%5D)
where,
and
are vapor pressures of liquid at
(in kelvin) and
(in kelvin) temperatures respectively.
Here,
= 760.0 mm Hg,
= 373 K,
= 314.0 mm Hg
Plug-in all the given values in the above equation:
![ln(\frac{314.0}{760.0})=\frac{-40.7\times 10^{3}\frac{J}{mol}}{8.314\frac{J}{mol.K}}\times [\frac{1}{T_{2}}-\frac{1}{373K}]](https://tex.z-dn.net/?f=ln%28%5Cfrac%7B314.0%7D%7B760.0%7D%29%3D%5Cfrac%7B-40.7%5Ctimes%2010%5E%7B3%7D%5Cfrac%7BJ%7D%7Bmol%7D%7D%7B8.314%5Cfrac%7BJ%7D%7Bmol.K%7D%7D%5Ctimes%20%5B%5Cfrac%7B1%7D%7BT_%7B2%7D%7D-%5Cfrac%7B1%7D%7B373K%7D%5D)
or, 
So, 
Hence, at base camp, water will boil at 