The relative volumes of chloroform and water that should be used is 9:10
Concentration of solution in chloroform =
( moles of chloroform )
Concentration of solution in water =
( moles of water )
Dissociation constant at
; 
Concentration of solution in chloroform / Concentration of solution in water
Meaning;

Since
mole is present in chloroform and
mole is present in water, Total mole of Caffeine present is 
Now, we substitute our given values into the equation

Therefore, the relative volumes of chloroform and water that should be used is 9:10
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I would say the first three. But I'm not 100% sure. I'm truly sorry if it's wrong
The molarity is a concentration unit which defined as the number of moles of solute divided by the number of liters of solution. So the molarity of the solution is 3/2=1.5 mol/L.
In the data, 0.20 ppm is an outlier and this can be rejected if there is a 95% confidence level.
<h3>What is an outlier?</h3>
When analyzing data an outlier is a value that is abnormal or too different from other data. In the case presented 0.20 can be tagged as an outlier because other values such as 0.11, 0.12, 0.13, and 0.14 are similar while 0.20 is outside this range.
<h3>Should this piece of data be rejected?</h3>
The general rule is that if there is a 95% of confidence or higher you can reject an outlier, knowing the other data occurs 95% of the time, and therefore the outlier is improbable.
Based on this, you can reject an outlier if the confidence level is 95%.
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