Calculate the change internal energy (ΔE) for a system that is giving off 65.0 kJ of heat and is performing 855 J of work on the
1 answer:
Answer: -64.1 kJ.
Explanation:
According to first law of thermodynamics:
=Change in internal energy
q = heat absorbed or released
w = work done or by the system
w = work done by the system= {Work is done by the system is negative as the final volume is greater than initial volume}
w = -855 Joules = 0.855 kJ (1kJ=1000J)
q = -65.0 kJ {Heat released by the system is negative}
Thus the change internal energy (ΔE) for a system that is giving off 65.0 kJ of heat and is performing 855 J of work on the surroundings is -64.1 kJ.
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</span>Reason:
1) As per Arrhenius theory, rate of chemical reactions is influence by temperature. Mathematically it is expressed as: k = A exp(-Ea/RT)
</span>where, k = rate constant, A = collision frequency, Ea = activation energy, T = temp. From above relation, it can be seen that, chemical reactions involving only liquids will be influenced temperature.
2) Also, if know that, rates of chemical reactions is mathematically expressed as:![Rate = [A]^{x} B^{y}....](https://tex.z-dn.net/?f=%20Rate%20%3D%20%5BA%5D%5E%7Bx%7D%20B%5E%7By%7D....%20%20)
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where A, B, .. are the reactants.
From above relation, it can be seen that, chemical reactions involving only liquids will be influenced concentration i.e. number of particle.
3) However, since all the reactant and catalyst used (if any) is in liquid state, particle size of same will not influence the reaction.
4) Also, since there are no gas-phase reactant, pressure will not affect the reaction.
</span>Reason:
1) As per Arrhenius theory, rate of chemical reactions is influence by temperature. Mathematically it is expressed as: k = A exp(-Ea/RT)
</span>where, k = rate constant, A = collision frequency, Ea = activation energy, T = temp. From above relation, it can be seen that, chemical reactions involving only liquids will be influenced temperature.
2) Also, if know that, rates of chemical reactions is mathematically expressed as:
where A, B, .. are the reactants.
From above relation, it can be seen that, chemical reactions involving only liquids will be influenced concentration i.e. number of particle.
3) However, since all the reactant and catalyst used (if any) is in liquid state, particle size of same will not influence the reaction.
4) Also, since there are no gas-phase reactant, pressure will not affect the reaction.