Answer: - 436.5 kJ.
Explanation:
According to Hess’s law of constant heat summation, the heat absorbed or evolved in a given chemical equation is the same whether the process occurs in one step or several steps.
According to this law, the chemical equation can be treated as ordinary algebraic expression and can be added or subtracted to yield the required equation.
The given chemical reaction is,

Now we have to determine the value of
for the following reaction i.e,

According to the Hess’s law, if we divide the reaction by half then the
will also get halved and on reversing the reaction , the sign of enthlapy changes.
So, the value
for the reaction will be:


Hence, the value of
for the reaction is -436.5 kJ.
Answer: The mass percentage of
is 5.86%
Explanation:
To calculate the mass percentage of
in the sample it is necessary to know the mass of the solute (
in this case), and the mass of the solution (pesticide sample, whose mass is explicit in the letter of the problem).
To calculate the mass of the solute, we must take the mass of the
precipitate. We can establish a relation between the mass of
and
using the stoichiometry of the compounds:

Since for every mole of Tl in
there are two moles of Tl in
, we have:

Using the molar mass of
we have:

Finally, we can use the mass percentage formula:

Answer:
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Explanation: