In the crystallization process the solid compound is dissolved in the solvent at elevated temperature and the crystallize product obtained by slow cooling of the solution. Here the solubility of acetanilide at 100°C is 1g per 20mL of water. Thus to dissolve 500mg of acetanilide at high temperature that is 100°C we need 10mL of water.
Now at 25°C after the re-crystallization there will be some amount of dissolve acetanilide. Which can be calculated as- 185mL of water is needed to dissolve 1g or 1000mg of acetanilide at 25°C. Thus in 10mL of water there will be
gmg of acetanilide.
Answer:
Its a natural resource used around the world
Answer:
a=28600J; b=90.6 J/K; c=402 torr
Explanation:
(a) considering the data given
Vapour pressure P1 =0 at Temperature T1 = 42.43˚C,
Vapour pressure P2 = 273.15 at Temperature T2= 315.58 K)
Using the Clausius-Clapeyron Equation
ln (P2/P1) = (ΔH/R)(1/T2 - 1/T1)
In 760/140 = ΔH/8.314 J/mol/K × (1/315.58K -- 1/273.15K)
ΔH vap= +28.6 kJ/mol or 28600J
(b) using the Equation ΔG°=ΔH° - TΔS to solve forΔS.
Since ΔG at boiling point is zero,
ΔS =(ΔH°vap/Τb)
ΔS = 28600 J/315.58 K
= 90.6 J/K
(c) using ln (P2/P1) = (ΔH/R)(1/T2 - 1/T1)
ln P298 K/1 atm = 28600 J/8.314 J/mol/K × (1/298.15K - 1/315.58K)
P298 K = 0.529 atm
= 402 torr