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sleet_krkn [62]
4 years ago
11

The sink-float method is often used to identify the type of glass material found at crime scenes by determining its density.

Chemistry
1 answer:
Olegator [25]4 years ago
8 0

Answer:

<em><u>Glass that will sink</u></em>

  • alkali zinc borosilicate with a density of 2.57 g/mL in a solution with a density of 2.46 g/mL

  • potash soda lead with a density of 3.05 g/mL in a solution with a density of 1.65 g/mL

<em><u>Glass that will float</u></em>

  • soda borosilicate with a density of 2.27 g/mL in a solution with a density of 2.62 g/mL

  • alkali strontium with a density of 2.26 g/mL in a solution with a density of 2.34 g/mL

<em><u>Glass that will not sink or float</u></em>

  • potash borosilicate with a density of 2.16 g/mL in a solution with a density of 2.16 g/mL

Explanation:

Density is the property of matter that states the ratio of the amount of matter, its mass, to the space occupied by it, its volume.

So, the mathematical expression for the density is:

  • density = mass / volume

By comparing the density of a material with the density of a liquid, you will be able to determine whether object will float, sink, or do neither when immersed in the liquid.

The greater the density of an object the more it will try to sink in the liquid.

As you must have experienced many times an inflatable ball (whose density is very low) will float in water, but a stone (whose denisty is greater) will sink in water.

The flotation condition may be summarized by:

  • When the density of the object < density of the liquid, the object will float
  • When the density of the object = density of the liquid: the object will neither float nor sink
  • When the density of the object > density of the liquid: the object will sink.

<em><u>Glass that will sink</u></em>

  • alkali zinc borosilicate with a density of 2.57 g/mL in a solution with a density of 2.46 g/mL, because 2.57 > 2.46.

  • potash soda lead with a density of 3.05 g/mL in a solution with a density of 1.65 g/mL, because 3.05 > 1.65.

<u><em>Glass that will float</em></u>

  • soda borosilicate with a density of 2.27 g/mL in a solution with a density of 2.62 g/mL, because 2.27 < 2.62.

  • alkali strontium with a density of 2.26 g/mL in a solution with a density of 2.34 g/mL, because 2.26 < 2.34.

<em><u>Glass that will not sink or float</u></em>

  • potash borosilicate with a density of 2.16 g/mL in a solution with a density of 2.16 g/mL, because 2.16 = 2.16
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Nicotine, a component of tobacco, is composed of C, H, and N. A 7.875-mg sample of nicotine was combusted, producing 21.363 mg o
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Answer: The empirical formula for the given compound is C_5H_7N

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The chemical equation for the combustion of compound having carbon, hydrogen, and nitrogen follows:

C_xH_yN_z+O_2\rightarrow CO_2+H_2O

where, 'x', 'y' and 'z' are the subscripts of carbon, hydrogen and nitrogen respectively.

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Molar mass of water = 18 g/mol

For calculating the mass of carbon:

In 44 g of carbon dioxide, 12 g of carbon is contained.

So, in 21363 g of carbon dioxide, \frac{12}{44}\times 21363=5826.27g of carbon will be contained.

For calculating the mass of hydrogen:

In 18 g of water, 2 g of hydrogen is contained.

So, in 6125 g of water, \frac{2}{18}\times 6125=680.55 of hydrogen will be contained.

Now we have to calculate the mass of nitrogen.

Mass of nitrogen in the compound = (7875) - (5826.27 + 680.55) = 1368.18 g

To formulate the empirical formula, we need to follow some steps:

Step 1: Converting the given masses into moles.

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Moles of Hydrogen = \frac{\text{Given mass of Hydrogen}}{\text{Molar mass of Hydrogen}}=\frac{680.55g}{1g/mole}=680.55moles

Moles of Nitrogen = \frac{\text{Given mass of nitrogen}}{\text{Molar mass of nitrogen}}=\frac{1368.18g}{14g/mole}=97.73moles

Step 2: Calculating the mole ratio of the given elements.

For the mole ratio, we divide each value of the moles by the smallest number of moles calculated which is 0.0154 moles.

For Carbon = \frac{485.52}{97.73}=4.96\approx 5

For Hydrogen  = \frac{680.55}{97.73}=6.96\approx 7

For Nitrogen = \frac{97.73}{97.73}=1

Step 3: Taking the mole ratio as their subscripts.

The ratio of C : H : N = 5 : 7 : 1

Hence, the empirical formula for the given compound nicotine is C_5H_7N_1=C_5H_7N

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Equilibrium will remain unaffected if the concentration of products and reactants are kept the same, and the temperature of the system is kept constant.

As the system is closed, we cannot add or remove products or reactants.

Change in temperature will shift the chemical equilibrium towards the reactant or product depending on whether the reaction is exothermic or endothermic.

Also change in volume  will shift the chemical equilibrium of a chemical reaction if the reactants or products or both are gases.

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