Burning splint test
2H2 (g) + O2 (g) -> 2H20 (g) + heat
It’s a combustion reaction
[Co(CN)₆]³⁻ → Yellow
[Co(NH₃)₆]³⁺ → Orange
[CoF₆]³⁻ → Blue
Explanation:
- All the given compounds have octahedral geometry but the ligand in each are different with the same metal ion.
- Ligands strength order: CN⁻ > NH₃ > F⁻
- The ligand CN will act as a strong field ligand so that the splitting is maximum when compared to NH₃ and F⁻
- If the splitting is more, the energy required for transition is more, and the wavelength is inversely proportional to energy.
- So CN complex will absorb at lower wavelength (yellow color)
Answer:
a. Kp=1.4


b.Kp=2.0 * 10^-4


c.Kp=2.0 * 10^5


Explanation:
For the reaction
A(g)⇌2B(g)
Kp is defined as:

The conditions in the system are:
A B
initial 0 1 atm
equilibrium x 1atm-2x
At the beginning, we don’t have any A in the system, so B starts to react to produce A until the system reaches the equilibrium producing x amount of A. From the stoichiometric relationship in the reaction we get that to produce x amount of A we need to 2x amount of B so in the equilibrium we will have 1 atm – 2x of B, as it is showed in the table.
Replacing these values in the expression for Kp we get:

Working with this equation:

This last expression is quadratic expression with a=4, b=-(4+Kp) and c=1
The general expression to solve these kinds of equations is:
(equation 1)
We just take the positive values from the solution since negative partial pressures don´t make physical sense.
Kp = 1.4


With x1 we get a partial pressure of:


Since negative partial pressure don´t make physical sense x1 is not the solution for the system.
With x2 we get:


These partial pressures make sense so x2 is the solution for the equation.
We follow the same analysis for the other values of Kp.
Kp=2*10^-4
X1=0.505
X2=0.495
With x1


Not sense.
With x2


X2 is the solution for this equation.
Kp=2*10^5
X1=50001

With x1


Not sense.
With x2


X2 is the solution for this equation.
Answer: (3) silicon
Explanation:
Element is a pure substance which is composed of atoms of similar elements.It can not be decomposed into simpler constituents using chemical reactions.Example: Silicon (Si)
Compound is a pure substance which is made from atoms of different elements combined together in a fixed ratio by mass.It can be decomposed into simpler constituents using chemical reactions. Example: ethane
, propanone
and water 