Which of the given will facilitate a normal Diels–Alder reaction?
1 answer:
Answer:
D
Explanation:
- The rate of the Diels-Alder is orders of magnitude faster if there is an electron-withdrawing group on the dienophile. For example, replacing a hydrogen on ethene with the electron-withdrawing group CN results in about a 10^5 increase in the reaction rate.
- Other common electron withdrawing functional groups that will accelerate the Diels Alder reaction of dienophiles include aldehydes, ketones, and esters.
- In short, any functional group conjugated with the pi bond which can act as a pi acceptor will accelerate a Diels-Alder reaction with a typical diene.
- See attachment for graphical explanation.
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To solve this exercise it is necessary to apply the concepts related to Robert Boyle's law where:
Where,
P = Pressure
V = Volume
T = Temperature
n = amount of substance
R = Ideal gas constant
We start by calculating the volume of inhaled O_2 for it:
Our values are given as
P = 1atm
T=293K
Using the equation to find n, we have:
Number of molecules would be found through Avogadro number, then
Answer:
The distance from Witless to Machmer is 438.63 m.
Explanation:
Given that,
Machmer Hall is 400 m North and 180 m West of Witless.
We need to calculate the distance
Using Pythagorean theorem
Where, =distance of Machmer Hall
=distance of Witless
Put the value into the formula
Hence, The distance from Witless to Machmer is 438.63 m.