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LUCKY_DIMON [66]
3 years ago
9

If 60.0 grams of carbonic acid are sealed in a 2.00 L soda bottle at room temperature (298 K) and decompose completely via the e

quation below, what would be the final pressure of carbon dioxide assuming it had the full 2.00 L in which to expand? H₂CO₃(aq) → H₂O(l) + CO₂(g)
Chemistry
1 answer:
Tresset [83]3 years ago
6 0

Answer:

The final pressure of the carbon dioxide gas will 11.84 atm.

Explanation:

Moles of carbonic acid = \frac{60.0 g}{62 g/mol}=0.9677 mol

H_2CO_3(aq)\rightarrow H_2O(l) + CO_2(g)

According to reaction, 1 mol of carbonic acid gives 1 mole of carbon dioxide gas.

Then 0.9677 moles of carbonic acid will give :

\frac{1}{1}\times 0.9677 mol=0.09677 mol of carbon dioxide

Moles of carbon dioxide gas = n = 0.09677 mol

Volume of soda bottle = V_1=2 L

Pressure of the carbon dioxide gas = P

Temperature of the carbon dioxide gas = T = 298 K

PV=nRT (ideal gas law)

P=\frac{nRT}{V}=\frac{0.9677 mol\times 0.0821 atm L/mol K\times 298 K}{2 L}=11.84 atm

The final pressure of the carbon dioxide gas will 11.84 atm.

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Answer:

\boxed{\text{-862 kJ/mol}}

Explanation:

One way to calculate the lattice energy is to use Hess's Law.

The lattice energy U is the energy released when the gaseous ions combine to form a solid ionic crystal:

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We must generate this reaction rom the equations given.

(1)  Li(s) + ½Cl₂ (g) ⟶ LiCl(s);      ΔHf°     = -409 kJ·mol⁻¹

(2) Li(s) ⟶ Li(g);                          ΔHsub =    161 kJ·mol⁻¹

(3) Cl₂(g) ⟶ 2Cl(g)                     BE        =   243 kJ·mol⁻¹

(4) Li(g) ⟶Li⁺(g) +e⁻                   IE₁         =   520 kJ·mol⁻¹

(5) Cl(g) + e⁻ ⟶ Cl⁻(g)                EA₁       =  -349 kJ·mol⁻¹

Now, we put these equations together to get the lattice energy.

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(5) Li⁺(g) +e⁻ ⟶ Li(g)                520

(6) Li(g) ⟶ Li(s)                         -161

(7) Li(s) + ½Cl₂(g) ⟶ LiCl(s)     -409

(8) Cl(g) ⟶ ½Cl₂(g)                   -121.5

(9) Cl⁻(g) ⟶ Cl(g) + e⁻               <u>+349</u>

      Li⁺(g) +  Cl⁻(g) ⟶ LiCl(s)     -862

The lattice energy of LiCl is \boxed{\textbf{-862 kJ/mol}}.

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