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Zina [86]
3 years ago
7

The decomposition of H2O2 is first order in H2O2 and the rate constant for this reaction is 1.63 x 10-4 s-1. How long will it ta

ke for [H2O2] to fall from 0.95 M to 0.33 M?
Chemistry
1 answer:
Mamont248 [21]3 years ago
3 0

Answer:

It will take 6486.92 minutes  for [H2O2] to fall from 0.95 M to 0.33 M

Explanation:

The order of reaction is defined as the sum of the powers of the concentration terms in the equation. Order of a reaction is given by the number of atoms or molecule whose concentration change during the reaction and determine the rate of reaction.

In first order reaction;

In \dfrac{a}{a_o-x}= k_1 t

where;

a = concentration at time t

a_o = initial concentration

and k = constant.

In (\dfrac{0.33}{0.95})= -1.63 \times 10^{-4} \times t

-1.05736933 = -1.63 \times 10^{-4} \times t

t = \dfrac{-1.05736933}{  -1.63 \times 10^{-4} }

t = 6486.92 minutes

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What is the concentration of NaCl in a solution if titration of 15.00 mL of the solution with 0.2503 M AgNO3 requires 20.22 mL o
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Answer:

The concentration of NaCl = 0.3374 M

Explanation:

Given :

Molarity of AgNO₃ = 0.2503 M

Volume of AgNO₃ = 20.22 mL

The conversion of mL into L is shown below:

1 mL= 10^{-3} L

Thus, volume of the solution = 20.22×10⁻³ L

Molarity of a solution is the number of moles of solute present in 1 L of the solution.

Molarity=\frac{Moles\ of\ solute}{Volume\ of\ the\ solution}

The formula can be written for the calculation of moles as:

Molarity=\frac{Moles\ of\ solute}{Volume\ of\ the\ solution}

Thus,  

Moles\ of\ AgNO_3 =Molarity \times {Volume\ of\ the\ solution}

Moles\ of\ AgNO_3 =0.2503 \times {20.22\times 10^{-3}}\ moles

Moles\ of\ AgNO_3 = 5.0611 \times 10^{-3} moles

The chemical reaction taking place:

AgNO_3_(aq) + NaCl_(aq) \rightarrow AgCl_(s) + NaNO_3_(aq)

According to reaction stoichiometry:

<u>1 mole</u> of AgNO₃ reacts with <u>1 mole</u> of NaCl

Thus,

5.0611×10⁻³ moles of AgNO₃ reacts with 5.0611×10⁻³ moles of NaCl

Thus, moles of NaCl required = 5.0611×10⁻³ moles

Volume of NaCl required = 15.00 mL

The conversion of mL into L is shown below:

1 mL= 10^{-3} L

Thus, volume of the solution = 15.00×10⁻³ L

Applying in the formula of molarity as:

Molarity=\frac{Moles\ of\ solute}{Volume\ of\ the\ solution}

Molarity\ of\ NaCl=\frac{5.0611\times 10^{-3}}{15.00\times 10^{-3}}

Molarity\ of\ NaCl= 0.3374 M

<u>Thus, the concentration of NaCl = 0.3374 M</u>

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