Answer: The gauge pressure in the tire when its temperature rises to 33◦C will be 28.7 lb/in2
Explanation: Please see the attachments below
Internal thermal energy is given as

so it will depend on the product of mass, specific heat capacity and temperature.
so here we know that both blocks are identical with same initial temperature
So the block with larger mass must have more internal energy
So here the correct answer would be the block with mass 1000g
block with mass 1000 g must have more internal energy