Answer:
3.5 atm
Explanation:
As stated in the question pressure is required to counteract the natural tendency for water to dilute the more concentrated solution. The difference in concentrations will give us the answer using the osmotic pressure equation.
π = ( n/v) RT where n/v is the molarity (mol/L), R is the gas constant and T is the temperature.
The difference in osmotic pressure of the solutions is:
Δπ = Δ c RT where c is the difference in molar concentrations.
pressure required = Δπ = (0.190 - 0.048) M x 0.821 Latm/Kmol x 298 K
= 3.47 atm
Answer: The value of
for chloroform is
when 0.793 moles of solute in 0.758 kg changes the boiling point by 3.80 °C.
Explanation:
Given: Moles of solute = 0.793 mol
Mass of solvent = 0.758

As molality is the number of moles of solute present in kg of solvent. Hence, molality of given solution is calculated as follows.

Now, the values of
is calculated as follows.

where,
i = Van't Hoff factor = 1 (for chloroform)
m = molality
= molal boiling point elevation constant
Substitute the values into above formula as follows.

Thus, we can conclude that the value of
for chloroform is
when 0.793 moles of solute in 0.758 kg changes the boiling point by 3.80 °C.
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<h3><u>Answer;</u></h3>
= 3032.15 kPa
<h3><u>Explanation;</u></h3>
Using the equation;
PV = nRT , where P is the pressure,. V is the volume, n is the number of moles and T is the temperature and R is the gas constant, 0.08206 L. atm. mol−1.
Volume = 7.5 L, T = 274 +273 = 547 K, N = 5 moles
Therefore;
Pressure = nRT/V
= (5 × 0.08206 × 547)/7.5 L
= 29.925 atm
But; 1 atm = 101325 pascals
Hence; Pressure = 3032150.63 pascals
<u>= 3032.15 kPa</u>