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Nikolay [14]
2 years ago
6

You can obtain a rough estimate of the size of a molecule with the following simple experiment: Let a droplet of oil spread out

on a fairly large but smooth water surface. The resulting "oil slick" that forms on the surface of the water will be approximately one molecule thick. Given an oil droplet with a mass of 9.00 × 10−7 kg and a density of 918 kg/m3 that spreads out to form a circle with a radius of 41.8 cm on the water surface, what is the approximate diameter of an oil molecule?
Chemistry
1 answer:
mina [271]2 years ago
6 0

Answer:

The diameter of the oil molecule is 4.4674\times 10^{-8} cm .

Explanation:

Mass of the oil drop = m=9.00\times 10^{-7} kg

Density of the oil drop = d=918 kg/m^3

Volume of the oil drop: v

d=\frac{m}{v}

v=\frac{m}{d}=\frac{9.00\times 10^{-7} kg}{918 kg/m^3}

Thickness of the oil drop is 1 molecule thick.So, let the thickness of the drop or diameter of the molecule be x.

Radius of the oil drop on the water surface,r = 41.8 cm = 0.418 m

1 cm = 0.01 m

Surface of the sphere is given as: a = 4\pi r^2

a=4\times 3.14\times (0.418 m)^2=2.1945 m^2

Volume of the oil drop = v = Area × thickness

\frac{9.00\times 10^{-7} kg}{918 kg/m^3}=2.1945 m^2\times x

x= 4.4674\times 10^{-10} m= 4.4674\times 10^{-8} cm

The thickness of the oil drop is 4.4674\times 10^{-8} cm and so is the diameter of the molecule.

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The empirical formula is the simplest formula of a chemical compound.

To find the empirical formula, we take the following steps;

  • Divide the percentage by mass of each element by its relative atomic mass.
  • Divide the quotient of each by the lowest value obtained instep 1 above
  • Write the result of step 2 above as the subscript following each atom.

1) O - 88.10/16,      H - 11.190/1

  O - 5.5,               H - 11.19

  O - 5.5/5.5,        H - 11.19/5.5

  O -  1,                 H - 2

Empirical formula = OH2

2) C - 41.368/12  H - 8.101/1,   N - 32.162/14,   O - 18.369/16

   C - 3,               H - 8,           N - 2,                  O - 1

   C - 3/1,            H - 8/1          N - 2/1                 O - 1/1

    C - 3,             H - 8,           N - 2,                   O - 1

Empirical formula = C3H8N2O

To obtain the molecular formula where n = number of atoms of each element;

Molecular weight = 174.204 g/mol

[ 3(12) + 8(1) + 2(14) + 16]n = 174

n= 174/88

n = 2 (to the nearest whole number)

Hence, we have;

[C3H8N2O]2

The molecular formula is C6H16N4O2

3)  C - 19.999/12,  H - 6.713/1,   N - 46.646/14,   O - 26.641/16

    C - 2,                H - 7,            N -  3,                 O - 2

    C - 2/2,            H - 7/2,         N -   3/2,             O - 2/2

    C - 1,                H - 4,            N -  2,                  O - 1

Empirical formula - CH4N2O

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3 years ago
A sample of PCl5(g) was placed in an otherwise empty flask at an initial pressure of 0.500 atm and a temperature above 500 K. Ov
tia_tia [17]

Answer:

Kp = 0.81666

Explanation:

Pressure of PCl₅ = 0.500 atm

Considering the ICE table for the equilibrium as:

                     PCl₅ (g)      ⇔          PCl₃ (g) +       Cl₂ (g)

t = o               0.500

t = eq                -x                             x                      x

--------------------------------------------- --------------------------

Moles at eq: 0.500-x                       x                      x

       

Given the pressure of PCl₅ at equilibrium = 0.150 atm

Thus, 0.500 - x = 0.150

x = 0.350 atm

The expression for the equilibrium constant is:

K_p=\frac {P_{PCl_3}P_{[Cl_2}}{P_{PCl_5}}  

So,

K_p=\frac{x^2}{0.500-x}  

x = 0.350 atm

Thus,

K_p=\frac{{0.350}^2}{0.500-0.350}  

<u>Thus, Kp = 0.81666</u>

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