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Shtirlitz [24]
3 years ago
13

Write a mechanism (using curved-arrow notation) for the deprotonation of tannins in base. Use Ar-OH as a generic form of a tanni

n and use sodium carbonate (Na2CO3) as the base. Balance the chemical equation. Comment on the aqueous solubilities of each species (assume that the tannin is insoluble in water initially)

Chemistry
1 answer:
Reika [66]3 years ago
7 0

Answer:

After deprotonation of tannin, tannin (Ar-OH) is converted to Ar-O^{-}Na^{+} salt which is soluble in water and CO_{3}^{2-} is converted to HCO_{3}^{-}Na^{+} which is also soluble in water

Explanation:

  • Sodium carbonate is a strong electrolyte which produces carbonate anion upon dissociation.
  • Carbonate ion is a strong conjugate base of weak acid HCO_{3}^{-}
  • After deprotonation of tannin, tannin (Ar-OH) is converted to Ar-O^{-}Na^{+} salt which is soluble in water and CO_{3}^{2-} is converted to HCO_{3}^{-}Na^{+} which is also soluble in water
  • Balanced equation: Ar-OH+Na_{2}CO_{3}\rightarrow Ar-O^{-}Na^{+}+Na^{+}HCO_{3}^{-}
  • Mechanism has been shown below.

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