Answer:
The rate law for second order unimolecular irreversible reaction is
![\frac{1}{[A]} = k.t + \frac{1}{[A]_{0} }](https://tex.z-dn.net/?f=%5Cfrac%7B1%7D%7B%5BA%5D%7D%20%3D%20k.t%20%2B%20%5Cfrac%7B1%7D%7B%5BA%5D_%7B0%7D%20%7D)
Explanation:
A second order unimolecular irreversible reaction is
2A → B
Thus the rate of the reaction is
![v = -\frac{1}{2}.\frac{d[A]}{dt} = k.[A]^{2}](https://tex.z-dn.net/?f=v%20%3D%20-%5Cfrac%7B1%7D%7B2%7D.%5Cfrac%7Bd%5BA%5D%7D%7Bdt%7D%20%3D%20k.%5BA%5D%5E%7B2%7D)
rearranging the ecuation
![-\frac{1}{2}.\frac{k}{dt} = \frac{[A]^{2}}{d[A]}](https://tex.z-dn.net/?f=-%5Cfrac%7B1%7D%7B2%7D.%5Cfrac%7Bk%7D%7Bdt%7D%20%3D%20%5Cfrac%7B%5BA%5D%5E%7B2%7D%7D%7Bd%5BA%5D%7D)
Integrating between times 0 to <em>t </em>and between the concentrations of
to <em>[A].</em>
![\int\limits^0_t -\frac{1}{2}.\frac{k}{dt} =\int\limits^A_{0} _A\frac{[A]^{2}}{d[A]}](https://tex.z-dn.net/?f=%5Cint%5Climits%5E0_t%20-%5Cfrac%7B1%7D%7B2%7D.%5Cfrac%7Bk%7D%7Bdt%7D%20%3D%5Cint%5Climits%5EA_%7B0%7D%20_A%5Cfrac%7B%5BA%5D%5E%7B2%7D%7D%7Bd%5BA%5D%7D)
Solving the integral
![\frac{1}{[A]} = k.t + \frac{1}{[A]_{0} }](https://tex.z-dn.net/?f=%5Cfrac%7B1%7D%7B%5BA%5D%7D%20%3D%20k.t%20%2B%20%5Cfrac%7B1%7D%7B%5BA%5D_%7B0%7D%20%7D)
That point is called as EQUILIBRIUM, and then you have to note that value to compare with others
Answer:
We'll have 1 mol Al2O3 and 3 moles H2
Explanation:
Step 1: data given
Numer of moles of aluminium = 2 moles
Number of moles of H2O = 6 moles
Step 2: The balanced equation
2Al + 3H2O → Al2O3 + 3H2
Step 3: Calculate the limiting reactant
For 2 moles Al we need 3 moles H2O to produce 1 mol Al2O3 and 3 moles H2
Aluminium is the limiting reactant. It will completely be consumed (2 moles).
H2O is in excess. There will react 3/2 * 2 = 3 moles
There will remain 6 - 3 = 3 moles
Step 4: Calculate moles products
For 2 moles Al we need 3 moles H2O to produce 1 mol Al2O3 and 3 moles H2
For 2 moles Al we'll have 2/1 = 1 mol Al2O3
For 2 moles Al We'll have 3/2 * 2 = 3 moles H2
We'll have 1 mol Al2O3 and 3 moles H2
Answer:
81.26% is the percent yield
Explanation:
Based on the reaction:
CaCl₂ + Na₂CO₃ → 2NaCl + CaCO₃
<em>Where 1 mole of CaCl₂ in excess of sodium carbonate produces 1 mole of calcium carbonate.</em>
<em />
To solve this question we must find the moles of CaCl2 added = Moles CaCO₃ produced (Theoretical yield). The percent yield is:
Actual yield (0.366g) / Theoretical yield * 100
<em>Moles CaCl₂ = Moles CaCO₃:</em>
0.0500L * (0.0900moles / L) = 0.00450 moles of CaCO₃
<em>Theoretical mass -Molar mass CaCO₃ = 100.09g/mol-:</em>
0.00450 moles of CaCO₃ * (100.09g / mol) = 0.450g of CaCO₃
Percent yield = 0.366g / 0.450g * 100
81.26% is the percent yield