The first bucket,because when we convert the both values in same units , we will observe that the temperature of first bucket is higher and second bucket is lower alternatively the kinetic energy in first bucket is higher and everything in it would move fast.

Multiply denominator and numerator of fraction by conjugate (2√7 -6)
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Expand using distributive property
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Collect like terms to simplify
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since we are looking at minutes per mile
45 min/8 miles = 5.625 minutes per mile