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3 years ago

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The mass of a substance is independent of the amount of the substance, while density depends on the amount of the substance. the

density of a substance is the volume of the substance per mass unit and has units such as l/kg, where volume has the units l and mass has units of kg. the density of a substance is independent of the amount of the substance, while mass depends on the amount of the substance. the density of a substance is the mass of the substance per volume unit and has units such as kg/l, where mass has units of kg and volume has the units l.

1 answer:

mart [117]3 years ago

6 0

Density is independent of amount while mass is dependent

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An equilibrium mixture of PCl5(g), PCl3(g), and Cl2(g) has partial pressures of 217.0 Torr, 13.2 Torr, and 13.2 Torr, respective

djverab [1.8K]

Answer:

The new partial pressures after equilibrium is reestablished for $PCl_3$ :

$P_1'=6.798 Torr$

The new partial pressures after equilibrium is reestablished $Cl_2$ :

$P_2'=26.398 Torr$

The new partial pressures after equilibrium is reestablished for $PCl_5$ :

$P_3'=223.402 Torr$

Explanation:

$PCl_3(g) + Cl_2(g)\rightleftharpoons PCl_5(g)$

At equilibrium before adding chlorine gas:

Partial pressure of the $PCl_3=P_1=13.2 Torr$

Partial pressure of the $Cl_2=P_2=13.2 Torr$

Partial pressure of the $PCl_5=P_3=217.0 Torr$

The expression of an equilibrium constant is given by :

$K_p=\frac{P_1}{P_1\times P_2}$

$=\frac{217.0 Torr}{13.2 Torr\times 13.2 Torr}=1.245$

At equilibrium after adding chlorine gas:

Partial pressure of the $PCl_3=P_1'=13.2 Torr$

Partial pressure of the $Cl_2=P_2'=?$

Partial pressure of the $PCl_5=P_3'=217.0 Torr$

Total pressure of the system = P = 263.0 Torr

$P=P_1'+P_2'+P_3'$

$263.0Torr=13.2 Torr+P_2'+217.0 Torr$

$P_2'=32.8 Torr$

$PCl_3(g) + Cl_2(g)\rightleftharpoons PCl_5(g)$

At initail

(13.2) Torr (32.8) Torr (13.2) Torr

At equilbriumm

(13.2-x) Torr (32.8-x) Torr (217.0+x) Torr

$K_p=\frac{P_3'}{P_1'\times P_2'}$

$1.245=\frac{(217.0+x)}{(13.2-x)(32.8-x)}$

Solving for x;

x = 6.402 Torr

The new partial pressures after equilibrium is reestablished for $PCl_3$ :

$P_1'=(13.2-x) Torr=(13.2-6.402) Torr=6.798 Torr$

The new partial pressures after equilibrium is reestablished $Cl_2$ :

$P_2'=(32.8-x) Torr=(32.8-6.402) Torr=26.398 Torr$

The new partial pressures after equilibrium is reestablished for $PCl_5$ :

$P_3'=(217.0+x) Torr=(217+6.402) Torr=223.402 Torr$

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Cannot be chemically broken down into simpler substances

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An element is the simplest form of matter that has a unique set of properties. Elements cannot be broken down into a simpler substance. Likewise, one element cannot be chemically converted into a different element.

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