Question

Consider these metal ion/metal standard reduction potentials Cd2+(aq)|Cd(s) Zn2+(aq)|Zn(s) Ni2+(aq)|Ni(s) Cu2+(aq)|Cu(s) Ag+(aq)|Ag(s) -0.40 V -0.76 V ‑0.25 V +0.34 V +0.80 V Based on the data above, which species is the best reducing agent?

Answer 1

Answer:

The best reducing agent is Zn(s)

Explanation:

A reducing agent must to be able to reduce another compound, by oxidizing itself. Consequently, the oxidation potential must be high. The oxidation potential of a compound is the reduction potential of the same compound  with the opposite charge. Given the reduction potentials, the best reducing agent will be the compound with the most negative reduction potential. Among the following reduction potentials:

Cd₂⁺(aq)|Cd(s) ⇒ -0.40 V

Zn²⁺(aq)|Zn(s) ⇒ -0.76 V

Ni²⁺(aq)|Ni(s) ⇒‑0.25 V

Cu²⁺(aq)|Cu(s) ⇒ +0.34 V

Ag⁺(aq)|Ag(s) ⇒ +0.80 V

The most negative is Zn²⁺(aq)|Zn(s) ⇒ -0.76 V

From this, the most reducing agent is Zn. Zn(s) is oxidized to Zn²⁺ ions with the highest oxidation potential (0.76 V).