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Aleks [24]
3 years ago
7

Determine the empirical formula for a compound that is 70.79% carbon, 8.91% hydrogen, 4.59% nitrogen, and 15.72% oxygen. determi

ne the empirical formula for a compound that is 70.79 carbon, 8.91 hydrogen, 4.59 nitrogen, and 15.72 oxygen. c18h27no2 c18h27no3 c17h27no3 c17h26no3
Chemistry
1 answer:
IceJOKER [234]3 years ago
5 0
Hello!

We use the amount in grams (mass ratio) based on the composition of the elements, see: (in 100g solution)

C: 70.79% = 70,79 g 
H: 8.91% = 8.91 g
N: 4.59% = 4.59 g
O: 15.72% = 15.72 g

Let us use the above mentioned data (in g) and values will be ​​converted to amount of substance (number of moles) by dividing by molecular mass (g / mol) each of the values, lets see:

C: \dfrac{70.79\:\diagup\!\!\!\!\!g}{12\:\diagup\!\!\!\!\!g/mol} \approx 5.89\:mol

H: \dfrac{8.91\:\diagup\!\!\!\!\!g}{1\:\diagup\!\!\!\!\!g/mol} = 8.91\:mol

N: \dfrac{4.59\:\diagup\!\!\!\!\!g}{14\:\diagup\!\!\!\!\!g/mol} \approx 0.328\:mol

O: \dfrac{15.72\:\diagup\!\!\!\!\!g}{16\:\diagup\!\!\!\!\!g/mol} = 0.9825\:mol

We note that the values ​​found above are not integers, so let's divide these values ​​by the smallest of them, so that the proportion is not changed, let's see:

C: \dfrac{5.89}{0.328}\to\:\:\boxed{C\approx 18}

H: \dfrac{8.91}{0.328}\to\:\:\boxed{H\approx 27}

N: \dfrac{0.328}{0.328}\to\:\:\boxed{N\approx 1}

O: \dfrac{0.9825}{0.328}\to\:\:\boxed{O\approx 3}

T<span>hus, the minimum or empirical formula found for the compound will be:

</span>\boxed{\boxed{C_{18}H_{27}N_1O_3\:\:or\:\:C_{18}H_{27}NO_3}}\end{array}}\qquad\checkmark

I hope this helps. =)
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Consider the titration of 40.0 mL of 0.200 M HClO4 by 0.100 M KOH. Calculate the pH of the resulting solution after the followin
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b) 7.00

c) 0.85

d) 12.15

e) 1.30

Explanation:

The neutralization reaction involved in the titration is:

HClO₄(aq) + KOH(aq) → KClO₄(aq) + H₂O(l)

According to the chemical equation, 1 mol of HClO₄ reacts with 1 mol of KOH (1 equivalent of acid with 1 equivalent of base). The moles are calculated from the product of the molar concentration (M) and the volume in liters.

We have the following moles of acid (HClO₄):

40.0 mL x 1 L/1000 mL = 0.04 L

0.200 mol/L x 0.04 L = 8 x 10⁻³ moles HClO₄

Since HClO₄ is a strong acid (completely dissociated into H⁺ and ClO₄⁻ ions), the moles of HClO₄ are equal to the moles of H⁺. Then, we can calculate the initial pH:

[H⁺] = 0.200 M → pH = -log [H⁺] = -log (0.200) = 0.70

Now, we calculate the pH after the addition of KOH. Since KOH is a strong base, the concentration of KOH is equal to the concentration of OH⁻ ions.

a) 0.0 mL

No KOH is added, so the pH is the initial pH: 0.70

b) 80.0 mL KOH

80.0 mL x 1 L/1000 mL = 0.08 L

0.100 mol/L x 0.08 L = 8 x 10⁻³ moles KOH = 8 x 10⁻³ moles OH⁻

After neutralization we have:

8 x 10⁻³ moles H⁺ - 8 x 10⁻³ moles OH⁻ = 0

The neutralization reaction is complete and there is no remaining H⁺ from the acid. The concentration of H⁺ is equal to the concentration of H⁺ of water:

[H⁺] = 1 x 10⁻⁷ M → pH = -log [H⁺] = -log (1 x 10⁻⁷) = 7.0

c) 10.0 mL KOH

10.0 mL x 1 L/1000 mL = 0.01 L

0.100 mol/L x 0.01 L = 1 x 10⁻³ moles KOH = 1 x 10⁻³ moles OH⁻

After neutralization we have:

8 x 10⁻³ moles H⁺ - 1 x 10⁻³ moles OH⁻ = 7 x 10⁻³ moles H⁺

The total volume is: V = 40.0 mL + 10.0 mL = 50 mL = 0.05 L

[H⁺] = 7 x 10⁻³ moles/0.05 L = 0.14  → pH = -log [H⁺] = -log (0.14) = 0.85

d) 100.0 mL KOH

100.0 mL x 1 L/1000 mL = 0.1 L

0.100 mol/L x 0.1 L = 0.01 moles KOH = 1 x 10⁻² moles OH⁻

After neutralization we have:

1 x 10⁻² moles OH⁻ - 8 x 10⁻³ moles H⁺ = 2 x 10⁻³ moles OH⁻

The total volume is: V = 40.0 mL + 100.0 mL = 140 mL = 0.14 L

[OH⁻] = 2 x 10⁻³ moles/0.14 L = 0.014  → pOH = -log [OH⁻] = -log (0.014) = 1.84

pH + pOH = 14 → pH = 14 - pOH = 14 - 1.84 = 12.15

e) 40.0 mL KOH

40.0 mL x 1 L/1000 mL = 0.04 L

0.100 mol/L x 0.04 L = 4 x 10⁻³ moles KOH = 4 x 10⁻³ moles OH⁻

After neutralization we have:

8 x 10⁻³ moles H⁺ - 4 x 10⁻³ moles OH⁻ = 4 x 10⁻³ moles H⁺

The total volume is: V = 40.0 mL + 40.0 mL = 80.0 mL = 0.08 L

[OH⁻] = 4 x 10⁻³ moles/0.08 L = 0.05 M  → pH = -log [H⁺] = -log (0.05) = 1.30

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3 years ago
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