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Inessa05 [86]
3 years ago
7

A chemical reaction takes place inside a flask submerged in a water bath. The water bath contains 8.10kg of water at 33.9 degree

s celsius . During the reaction 69.0kJ of heat flows out of the bath and into the flask.
Calculate the new temperature of the water bath. You can assume the specific heat capacity of water under these conditions is 4.18J*g*K. Round your answer to 3 significant digits.
Chemistry
1 answer:
victus00 [196]3 years ago
5 0

Explanation:

The given data is as follows.

        q = 69.0 kJ = 69000 J (as 1 kJ = 1000 J),

       mass (m) = 8.10 kg = 8100 g  (as 1 kg = 1000 g)

        T_{i} = 33.9^{o}C = (33.9 + 273) K = 306.9 K

         C = 4.18 J/gK

As we know that the relation between heat and change in temperature is as follows.

                   q = m \times C \times \Delta T

Putting the values into the above formula to calculate the final temperature as follows.

                  q = m \times C \times \Delta T

       69000 J = 8100 g \times 4.18 J/g K \times (T_{f} - 306.9 K)                

           69000 J = 33858 \times (T_{f} - 306.9 K)

                  (T_{f} - 306.9 K) = 2.037 K

                    T_{f} = (2.037 + 306.9) K

                                  = 308.9 K

or,                               = 309 K (approx)

Thus, we can conclude that the new temperature of the water bath is 309 K.

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4 years ago
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Pentaborane-9, B5H9, is a colorless, highly reactive liquid that will burst into flame when exposed to oxygen. The reaction is 2
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<u>Answer:</u> The amount of energy released per gram of B_5H_9 is -71.92 kJ

<u>Explanation:</u>

For the given chemical reaction:

2B_5H_9(l)+12O_2(g)\rightarrow 5B_2O_3(s)+9H_2O(l)

The equation used to calculate enthalpy change is of a reaction is:  

\Delta H^o_{rxn}=\sum [n\times \Delta H^o_f_{(product)}]-\sum [n\times \Delta H^o_f_{(reactant)}]

The equation for the enthalpy change of the above reaction is:

\Delta H^o_{rxn}=[(5\times \Delta H^o_f_{(B_2O_3(s))})+(9\times \Delta H^o_f_{(H_2O(l))})]-[(2\times \Delta H^o_f_{(B_5H_9(l))})+(12\times \Delta H^o_f_{(O_2(g))})]

Taking the standard enthalpy of formation:

\Delta H^o_f_{(B_2O_3(s))}=-1271.94kJ/mol\\\Delta H^o_f_{(H_2O(l))}=-285.83kJ/mol\\\Delta H^o_f_{(B_5H_9(l))}=73.2kJ/mol\\\Delta H^o_f_{(O_2(g))}=0kJ/mol

Putting values in above equation, we get:

\Delta H^o_{rxn}=[(5\times (1271.94))+(9\times (-285.83))]-[(2\times (73.2))+(12\times (0))]\\\\\Delta H^o_{rxn}=-9078.57kJ

We know that:

Molar mass of pentaborane -9 = 63.12 g/mol

By Stoichiometry of the reaction:

If 2 moles of B_5H_9 produces -9078.57 kJ of energy.

Or,

If (2\times 63.12)g of B_5H_9 produces -9078.57 kJ of energy

Then, 1 gram of B_5H_9 will produce = \frac{-9078.57kJ}{(2\times 63.12)}\times 1g=-71.92kJ of energy.

Hence, the amount of energy released per gram of B_5H_9 is -71.92 kJ

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