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3 years ago

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A thin partition divides a thermally insulated vessel into a lower compartment of volume V and an upper compartment of volume 2V

. The lower compartment contains n moles of an ideal gas; the upper part is evacuated.When the partition is removed, the gas expands and fills both compartments. How many moles n of gas were initially contained in the lower compartment if the entropy change of the gas in this free-expansion process is 17.28 J/K?

1 answer:

Anni [7]3 years ago

6 0

Answer:

1.89mol

Explanation:

The entropy change during free expansion is express as

$S_{f}-S_{i}=nRln(\frac{V_{F}}{V_{I}})\\$

Where S is the entropy of the system,

n is the amount of mole

R is the gas constant = 8.314 and

V is the volume occupied at the initial and final stage

since the process is n adiabatic free expansion, the entropy of the system is constant. Hence we can re-write the equation as

$S=nRln(\frac{V_{F}}{V_{I}})\\$

where the $V_{i}=v\\$ and $V_{f}=2v+v=3v\\$

$S=17.28J/k\\$ and

$R=8.314\\$

Now if we substitute in values we arrive at

$17.28=(8.314)n*ln(\frac{3v}{v} )\\17.28=(8.314)n*ln(3 )\\17.28=(8.314)n*1.0986\\n=\frac{17.28}{8.314*1.0989}\\n=1.89 mole\\$

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With acceleration

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the velocity at time <em>t</em> (b) is given by

$\mathbf v(t)=\mathbf v(0)+\displaystyle\int_0^t\mathbf a\,\mathrm du$

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$\mathbf v(t)=\left(8.00\dfrac{\rm m}{\rm s}\right)\,\mathbf i+\left(2.00\dfrac{\rm m}{\mathrm s^2}\right)u\,\mathbf j\bigg|_{u=0}^{u=t}$

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We can get the position at time <em>t</em> (a) by integrating the velocity:

$\mathbf x(t)=\mathbf x(0)+\displaystyle\int_0^t\mathbf v(u)\,\mathrm du$

The particle starts at the origin, so $\mathbf x(0)=\mathbf0$ .

$\mathbf x(t)=\displaystyle\int_0^t\left(8.00\dfrac{\rm m}{\rm s}\right)\,\mathbf i+\left(2.00\dfrac{\rm m}{\mathrm s^2}\right)u\,\mathbf j\,\mathrm du$

$\mathbf x(t)=\left(\left(8.00\dfrac{\rm m}{\rm s}\right)u\,\mathbf i+\dfrac12\left(2.00\dfrac{\rm m}{\mathrm s^2}\right)u^2\,\mathbf j\right)\bigg|_{u=0}^{u=t}$

$\mathbf x(t)=\left(8.00\dfrac{\rm m}{\rm s}\right)t\,\mathbf i+\left(1.00\dfrac{\rm m}{\mathrm s^2}\right)t^2\,\mathbf j$

Get the coordinates at <em>t</em> = 8.00 s by evaluating $\mathbf x(t)$ at this time:

$\mathbf x(8.00\,\mathrm s)=\left(8.00\dfrac{\rm m}{\rm s}\right)(8.00\,\mathrm s)\,\mathbf i+\left(1.00\dfrac{\rm m}{\mathrm s^2}\right)(8.00\,\mathrm s)^2\,\mathbf j$

$\mathbf x(8.00\,\mathrm s)=(64.0\,\mathrm m)\,\mathbf i+(64.0\,\mathrm m)\,\mathbf j$

so the particle is located at (<em>x</em>, <em>y</em>) = (64.0, 64.0).

Get the speed at <em>t</em> = 8.00 s by evaluating $\mathbf v(t)$ at the same time:

$\mathbf v(8.00\,\mathrm s)=\left(8.00\dfrac{\rm m}{\rm s}\right)\,\mathbf i+\left(2.00\dfrac{\rm m}{\mathrm s^2}\right)(8.00\,\mathrm s)\,\mathbf j$

$\mathbf v(8.00\,\mathrm s)=\left(8.00\dfrac{\rm m}{\rm s}\right)\,\mathbf i+\left(16.0\dfrac{\rm m}{\rm s}\right)\,\mathbf j$

This is the <em>velocity</em> at <em>t</em> = 8.00 s. Get the <em>speed</em> by computing the magnitude of this vector:

$\|\mathbf v(8.00\,\mathrm s)\|=\sqrt{\left(8.00\dfrac{\rm m}{\rm s}\right)^2+\left(16.0\dfrac{\rm m}{\rm s}\right)^2}=8\sqrt5\dfrac{\rm m}{\rm s}\approx17.9\dfrac{\rm m}{\rm s}$

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