KH₂PO₄ hydrolyzes as;
H₂PO₄⁻ + H₂O ↔ H₃PO₄ + OH⁻
Let x amount of H₂PO₄⁻ has reacted with water then,
Kb₁ = [H₃PO₄][OH⁻] / [H₂PO₄⁻]
[H₂PO₄⁻] = 0.8-x M
Kb₁ = x² / (0.8 - x)
Given Ka₁ = 7.5 x 10⁻³
so Kb₁ = 1 x 10⁻¹⁴ / (7.5 x 10⁻³) = 1.33 x 10⁻¹²
From this information:
1.33 x 10⁻¹² = x² / 0.8
x = [OH⁻] = 1.03 x 10⁻⁶ M
pOH = - log (1.03 x 10⁻⁶) = 5.99
pH = 14 - pOH = 14 - 5.99 = 8.01
Graduated cylinder
Stopwatch
Thermometer
Molarity = moles of solute/volume of solution in liters.
From this relation, we can figure out the number of moles of solute by multiplying the molarity of the solution by the volume in liters.
We have 53.1 mL, or 0.0531 L, of a 12.5 M, or 12.5 mol/L, solution. Multiplying 12.5 mol/L by 0.0531 L, we obtain 0.664 moles. So, in this volume of solution, there are 0.664 moles of solute (HCl).