A change in pressure will affect the equilibrium position of the reaction if one or more of the reactants or products are in the gaseous phase.
Le Chatelier's principle states that whenever a change is brought about to a system under chemical equilibrium, the equilibrium shifts in a manner to reverse this change. So if the pressure of a reaction mixture is increased, the equilibrium will shift towards the side with the lower number of molecules, and if the pressure is reduced, the equilibrium will shift to the side with the greater number of molecules.
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Answer:
The net change in enthalpy for the formation of one mole of acrylic acid from calcium carbide, water and carbon dioxide is -470.4 kJ/mol.
Explanation:
Step 1 : Calcium carbide and water react to form acetylene and calcium hydroxide

..[1]
Step 2 : Acetylene, carbon dioxide and water react to form acrylic acid
..[2]
Using Hess's law:
[1] × 6 + [2]



The energy released on formation of 5 moles of acrylic acid = -2352 kJ
The energy released on formation of 1 moles of acrylic acid :

Hence, the net change in enthalpy for the formation of one mole of acrylic acid from calcium carbide, water and carbon dioxide is -470.4 kJ/mol.