These problems are a bit interesting. :)
First let's write the molecular formula for ammonium carbonate.
NH4CO3 (Note! The 4 and 3 are subscripts, and not coefficients)
17.6 gNH4CO3
Now to convert to mol of one of our substances we take the percent composition of that particular part of the molecule and multiply it by our starting mass. This is what it looks like using dimensional analyse.
17.6 gNH4CO3 * (Molar Mass of NH4 / Molar Mass of NH4CO3)
Grab a periodic table (or look one up) and find the molar masses for these molecules! Well. In this case I'll do it for you. (Note: I round the molar masses off to two decimal places)
NH4 = 14.01 + 4*1.01 = 18.05 g/mol
NH4CO3 = 14.01 + 4*1.01 + 12.01 + 3*16.00 = 78.06 g/mol
17.6 gNH4CO3 * (18.05 molNH4 / 78.06 molNH4CO3)
= 4.07 gNH4
Now just take the molar mass we found to convert that amount into moles!
4.07 gNH4 * (1 molNH4 / 18.05 gNH4) = 0.225 molNH4
Answer:

Explanation:
Hello there!
In this case, sine the solution of this problem require the application of the Raoult's law, assuming heptane is a nonvolatile solute, so we can write:

Thus, we first calculate the mole fraction of chloroform, by using the given masses and molar masses as shown below:

Therefore, the partial pressure of chloroform turns out to be:

Regards!
The redox reaction is

Here
Calcium undergoes reduction, and acts as cathode
Lithium undergoes oxidation and acts as anode
The reduction potential of calcium is -2.87 V
The reduction potential of lithium is - -3.05 V
We know that
Ecell = Ecathode - Eanode
Ecell = -2.87 - (-3.05) = 0.18 V