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Brilliant_brown [7]
2 years ago
13

2.1. Three moles of an ideal gas (with temperature-independent CP = (7/2)R, CV = (5/2)R) is contained in a horizontal piston/cyl

inder arrangement. The piston has an area of 0.1 m2 and mass of 500 g. The initial pressure in the piston is 101 kPa. Determine the heat that must be extracted to cool the gas from 375°C to 275°C at: (a) constant pressure; (b) constant volume.
Chemistry
1 answer:
Alenkasestr [34]2 years ago
6 0

Answer:

The answers to the question are

The heat that must be extracted to cool the gas from 375°C to 275°C at

(a) Constant pressure Q = -6110.78 J

(b) Constant volume Q = -4365 J

Explanation:

Cp = (7/2)R

CV = (5/2)R)

Area of piston = 0.1 m²

Mass of piston, m = 500 g =0.5 kg

Mass of piston = 500 g

Initial pressure of piston p₁ = 101 kPa

Initial temperature of piston = 375 °C = 648.15‬ K

Final temperature of piston =275 °C  = ‪‪548.15‬ K

Pressure from the piston = m×g/0.1 =0.5×9.81/0.1 = 49.05 Pa

Pressure from gas alone = 101000-49.05= 100950.95 Pa

Therefore we have from the general gas equation

P₁V₁ = n·R·T₁ Where

V₁ = Initial volume piston = n·R·T₁/P₁  R = 8.314 J / mol·K.

V₁ = (8.314×2.1×648.15)/100950.95 = 0.112097  m³

For V₂ =n·R·T₂/P₂ = (8.314×2.1×548.15)/101000 = 0.094756 m³

\frac{V_1}{V_2} = \frac{T_1}{T_2} V₂ = T₂/T₁×V₁ = 548.15/648.15×0.11204  = 0.09476 m³

But p·V = m·R·T ⇒ m·R = P·V/T =100950.95*0.112097/648.15 = 17.45938

For constant pressure we have Q = m*cp*(T₂-T₁) =7/2·R*m*(T₂-T₁) =

7/2*17.45938*(548.15 -648.15) = -6110.7838 J =

(b) At constant volume, the heat that must be extracted =

We have P₁/T₁ = P₂/T₂

m*cv*(T₂-T₁)

= 5/2·R*m*(548.15-648.15) =5/2*17.46*(-100) = -4365 J

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m_a_m_a [10]

The balanced chemical equation is :

5P₄ + 36OH → 12HPO₃⁻² (aq) + 8PH₃ (acidic)

Here the oxidation number of P changed from 0 to -3 in PH₃ and increases  from 0 to +3 in HPO₃⁻². When P₄ changes to PH₃ reduction reaction is taking place as there is addition of hydrogen and when P₄ changes to HPO₃⁻² oxidation takes place as there is addition of oxygen.

Thus clearly both reduction and oxidation are taking place.

Thus, we can infer that here P₄ is both oxidizing as well as reducing agent.

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5 0
1 year ago
There are 50 fish in the pond that have tags. You catch 25 fish, and 5 of them have tags. What is the best estimate of the numbe
sergeinik [125]

Answer: 250


Explanation:


You work this problem by using proportions.


A proportion is the equalization of two ratios.


Here you assume that the ratio of fish with tags to total fish that you catch is the same than the ratio of fish with tags to total fish in the pond.


Mathematically:

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Solve for x:

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Answer:

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2 years ago
Can someone solve this for me I'm confused.
Artemon [7]

Answer:

310.53 g of Cu.

Explanation:

The balanced equation for the reaction is given below:

CuSO₄ + Zn —> ZnSO₄ + Cu

Next, we shall determine the mass of CuSO₄ that reacted and the mass Cu produced from the balanced equation. This can be obtained as follow:

Molar mass of CuSO₄ = 63.5 + 32 + (16×4)

= 63.5 + 32 + 64

= 159.5 g/mol

Mass of CuSO₄ from the balanced equation = 1 × 159.5 = 159.5 g

Molar mass of Cu = 63.5 g/mol

Mass of Cu from the balanced equation = 1 × 63.5 = 63.5 g

Summary:

From the balanced equation above,

159.5 g of CuSO₄ reacted to produce 63.5 g of Cu.

Finally, we shall determine the mass of Cu produced by the reaction of 780 g of CuSO₄. This can be obtained as follow:

From the balanced equation above,

159.5 g of CuSO₄ reacted to produce 63.5 g of Cu.

Therefore, 780 g of CuSO₄ will react to produce = (780 × 63.5)/159.5 = 310.53 g of Cu.

Thus, 310.53 g of Cu were obtained from the reaction.

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dimaraw [331]
El agua con hielo es sistema heterogénea .
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