Answer:
pH = 2.69
Explanation:
The complete question is:<em> An analytical chemist is titrating 182.2 mL of a 1.200 M solution of nitrous acid (HNO2) with a solution of 0.8400 M KOH. The pKa of nitrous acid is 3.35. Calculate the pH of the acid solution after the chemist has added 46.44 mL of the KOH solution to it.</em>
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The reaction of HNO₂ with KOH is:
HNO₂ + KOH → NO₂⁻ + H₂O + K⁺
Moles of HNO₂ and KOH that react are:
HNO₂ = 0.1822L × (1.200mol / L) = <em>0.21864 moles HNO₂</em>
KOH = 0.04644L × (0.8400mol / L) = <em>0.0390 moles KOH</em>
That means after the reaction, moles of HNO₂ and NO₂⁻ after the reaction are:
NO₂⁻ = 0.03900 moles KOH = moles NO₂⁻
HNO₂ = 0.21864 moles HNO₂ - 0.03900 moles = 0.17964 moles HNO₂
It is possible to find the pH of this buffer (<em>Mixture of a weak acid, HNO₂ with the conjugate base, NO₂⁻), </em>using H-H equation for this system:
pH = pKa + log₁₀ [NO₂⁻] / [HNO₂]
pH = 3.35 + log₁₀ [0.03900mol] / [0.17964mol]
<h3>pH = 2.69</h3>
Answer:
Heat transfer in step 2 = 47.75 J
Explanation:
Internal energy = heat + work done
U = Q + W
In a cyclic process the total internal energy change of the system = 0.
In the process there are two steps. The total heat exchange in the process is the sum of heat exchanges in the two processes.
We have to find the heat exchange in step 2.
In step 1,
W = 1.25 J Q = -37 J
= -37 + 1.25 = -35.75 J
In step 2, the internal energy change will be negative of that in step 1.
U = 35.75 J
W = -12 J
U = Q + W
35.75 = Q -12
Q = 47.75 J
Heat transfer in step 2 = 47.75 J
Answer:
the relation of two different forms of the same substance (such as two allotropic forms of tin) that have a definite transition point and can therefore change reversibly each into the other — compare monotropy.
Fluorite is harder than gypsum but softer than apatite. Thus, the correct option is B.
<h3>What is the hardness of any element?</h3>
The hardness of any element may be defined as the capability of a material to oppose the process of deformation and remains in actual shape precisely.
According to the table of hardness scales by Mohs, the increasing order of given hardness of given elements is as follows:
Gypsum < Fluorite < Apatite.
Therefore, Fluorite is harder than gypsum but softer than apatite. Thus, the correct option is B.
To learn more about the Hardness of elements, refer to the link:
brainly.com/question/23721736
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You always adjust numbers and it will be before the element
so you Neva add or change a subscript