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miskamm [114]
3 years ago
11

An unknown triprotic acid (H3A) is titrated with NaOH. After the titration Ka1 is determined to be 0.0013 and Ka2 is determined

to be 6.5e-07. The pH at the second equivalence point of the titration is measured as 8.181. What is Ka3 for this triprotic acid
Chemistry
1 answer:
e-lub [12.9K]3 years ago
7 0

Answer:

6.68 X 10^-11

Explanation:

From the second Ka, you can calculate pKa = -log (Ka2) = 6.187

The pH at the second equivalence point (8.181) will be the average of pKa2  and pKa3. So,

8.181 = (6.187 + pKa3) / 2

Solving gives pKa3 = 10.175, and Ka3 = 10^-pKa3 = 6.68 X 10^-11

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What is the volume of HCl gas required to react with excess magnesium metal to produce 6.82 L of hydrogen gas at 2.19 atm and 35
prohojiy [21]

Answer:

Explanation:

2 HCl(g) + Mg(s) → MgCl₂(s) + H₂(g)

Let's calculate the quantity of mole of produced hydrogen with the Ideal Gases Law

P . V = n . R .T

2.19 atm . 6.82L = n . 0.082 . 308K

(2.19 atm . 6.82L) / (0.082 . 308K) = n

0.591 mol = n

1 mol of H₂ gas came from 2 mol of hydrochloric, so, 0.591 mol came from the double of mole

0.591 .2 = 1.182 mole of acid.

Molar mass of HCl = 36.45 g/m

1.182 mole are (36.45 g/m . 1.182g ) contained in 43.1 g

Density HCl = HCl mass / HCl volume

0,118 g/mL = 43.1 g / HCl volume

43.1 g / 0.118 g/mL = 365.3 mL (HCl volume)

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Gather and respond to information
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Sodium peroxide (Na2O2) is often used in self-contained breathing devices, such as those used in fire emergencies, because it re
Anastaziya [24]

Answer:

725.15 L

Explanation:

The balanced chemical equation for the reaction between Na₂O₂ and CO₂ is the following:

Na₂O₂ + CO₂ → Na₂CO₃ + 1/2 O₂

From the stoichiometry of the reaction, 1 mol of Na₂O₂ reacts with 1 mol CO₂. So, the stoichiometric ratio is 1 mol Na₂O₂/1 CO₂.

Now, we convert the mass of reactants to moles by using the molecular weight (Mw) of each compound:

Mw (Na₂O₂) = (23 g/mol x 2) + (16 g/mol x 2) = 78 g/mol

moles Na₂O₂ = 96.7 g/(78 g/mol) = 1.24 mol Na₂O₂

Mw (CO₂) = 12 g/mol + (16 g/mol x 2) = 44 g/mol

moles CO₂ = 0.0755 g/(44 g/mol) = 1.71 x 10⁻³ mol CO₂

Now, we calculate the number of moles of CO₂ we need to completely react with the mass of Na₂O₂ we have:

1.24 mol Na₂O₂ x 1 mol CO₂/1 mol Na₂O₂ = 1.24 mol CO₂

In 1 L of respired air we have 1.71 x 10⁻³ mol CO₂ (0.0755 g), so we need the following number of liters to have 1.24 mol of CO₂:

1.24 mol CO₂ x 1 L/1.71 x 10⁻³ mol CO₂ = 725.15 L

4 0
3 years ago
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