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andriy [413]
3 years ago
13

The proposed mechanism for a reaction is: Step 1: A + B X (fast) Step 2: X + C Y (slow) Step 3: Y D (fast) What is the overall r

eaction?
Chemistry
1 answer:
PolarNik [594]3 years ago
5 0

Answer:

(slow)xy2+z→xy2z (fast) c step1:step2:xy2+z2→xy2z2

Explanation:

Step1: xy2+z2→xy2z2 (slow)

Step2: xy2z2→xy2z+z (fast)

2XY 2 + Z 2 → 2XY 2 Z

Rate= k[xy2][z2]

 

When the two elementary steps are summed up, the result is equivalent to the stoichiometric equation. Hence, this mechanism is acceptable. The order of both elementary steps is 2, which is ‘≤3’; this also makes this mechanism acceptable. Furthermore, the rate equation aligns with the experimentally determined rate equation, and this also makes this mechanism acceptable. Therefore, since all the three rules have been observed, this mechanism is possible.

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3 years ago
Phosgene is formed from carbon monoxide and chlorine. At 611 oC, Kc is approximately 16.5 M-1 or L/mol. Calculate Kp (in atm-1)
defon

Answer:

Kp is 0.228/atm

Explanation:

This is the reaction:

CO + Cl<u>₂</u> → CCl₂O

1 mol of carbon monoxide and 1 mol of chlorine produce 1 mol of phosgene.

Formula for Kp which derivates from Kc is:

Kp = Kc (R.T)ⁿᵇ ⁻ ⁿᵃ

Δп = nb (moles in the products) - nₐ(moles in the reactants)

Δп = 1 - 2 = -1

T is T° in K → T°C + 273 = 611°C +273 = 884K

R → Universal constant gas → 0.082 L.atm/mol.K

We replace the data: Kp = 16.5 L/mol (0.082 . 884K)⁻¹ → 0.228/atm

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Once molecules are close enough to touch, intermolecular forces are
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