Answer:
<em>The pH of the solution is 7.8</em>
Explanation:
The concentration of the solution is 0.001M and the dye could be in its protonated and deprotonated forms. If the concentration of the protonated form [HA] is 0.0002 M the concentration of the deprotonated form will be the subtraction between the concentration of the bye and the concentration of the protonated form:
[A-] = 0.001M - 0.0002M = 0.0008M
Also, the Henderson-Hasselbalch equation is
this equation shows the dependency between the pH of the solution, the pKa and the concentration of the protonated and deprotonated forms. Thus, replacing in the equation
We can calculate years by using the half-life equation. It is expressed as:
A = Ao e^-kt
<span>where A is the amount left at t years, Ao is the initial concentration, and k is a constant.
</span>From the half-life data, we can calculate for k.
1/2(Ao) = Ao e^-k(1620)
<span>k = 4.28 x 10^-4
</span>
0.125 = 1 e^-<span>4.28 x 10^-4 (</span>t)
t = 4259 years
The 2nd one I believe
Answer- 2nd