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neonofarm [45]
3 years ago
12

Which one of the following best represents the predicted approximate chemical shift and coupling for the hydrogen(s) indicated w

ith the arrow?1.00 ppm, quartet 2.40 ppm, singlet 2.40 ppm, quartet 3.00 ppm, quartet 2.40 ppm, triplet

Chemistry
1 answer:
melomori [17]3 years ago
5 0

Answer:

The answer is quartet 2.40 ppm.

Note: Kindly find an attached image below for the part of the solution to this question

Sources: The image was researched from Course hero platform

Explanation:

Solution

Multiplicity or (n+1) rule:

It helps in determination of multiplicity of an individual proton or individual types of proton which are available in the molecule.

Multiplicity =(n+1)

Thus

The non equivalent protons which are attached from adjacent atom is denoted by n.

Now because there are three non-equivalent protons are present at adjacent carbon of methylene group, hence the multiplicity of methylene hydrogen is given as follows:

The multiplicity will be the same for the two hydrogen's. thus we compute multiplicity only for one  hydrogen atom stated below:

Non- equivalent = 3

Multiplicity = (3 +1)

= 4

= Quartet for 2H

A quartet for 2H indicates that the hydrogen atoms attached from the carbon, which is attached one side from a methyl group and the other side form an atom that have no any hydrogens.

Now due +I effect of carbonyl group, chemical shift value is high for these two hydrogens which is exactly at 2.40 ppm or 2.40 Quartet.

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