Answer:
Explanation:
The expression for Clausius-Clapeyron Equation is shown below as:
Where,
P is the vapor pressure
ΔHvap is the Enthalpy of Vaporization
R is the gas constant (8.314×10⁻³ kJ /mol K)
c is the constant.
For two situations and phases, the equation becomes:
Given:
= 13.95 torr
= 144.78 torr
= 25°C
The conversion of T( °C) to T(K) is shown below:
T(K) = T( °C) + 273.15
So,
T = (25 + 273.15) K = 298.15 K
= 298.15 K
= 75°C = 348.15 K
So,
i. The given compound X is 2-methyl pent-2-ene. When it is reacted with ozone it forms an ozonide in the first step. In the second step the reduce to forms acetone and propanal.
ii. The structural formula of Y is and Z is
.
iii. Alkenes, upon catalytic hydrogenation, form alkanes. This will occur in the presence of Nickel as the catalyst.
iv. The process of ozonolysis is useful in the field of pharmaceutics.
v. The test of unsaturation can be performed by passing a compound through Bromine water.
<h3>What is ozonolysis?</h3>Ozonolysis is a reaction used in organic chemistry to determine the position of a carbon-carbon double bond in unsaturated compounds.
i. The given alkene X, that is subject to ozonolysis would be 2-methyl-2-pentene. Upon exposure to ozone, an ozonide is initially formed, after which it is broken down into 2 products - acetone and propanal, both with the molecular formula C₃H₆O.
The given compound X is 2-methyl pent-2-ene. When it is reacted with ozone it forms an ozonide in the first step. In the second step the reduce to forms acetone and propanal.
ii. The formulas of Y is and Z is
. They are functional isomers as they have the same molecular formula but different functional groups - ketone and aldehyde.
iii. When alkenes undergo catalytic hydrogenation, they form alkanes, X will form 2 methyl petane on reaction with hydrogen gas in presence of Ni.
iv. The ozonolysis is used for the industrial-scale synthesis of pharmaceuticals.
v. The unsaturation of compound X can be proved by the bromine water test. As on reaction with it, the brown colour of bromine water becomes colourless due to the formation of dibromo alkane.
Learn more about the ozonolysis here:
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Answer:
The molarity is 0.56
Explanation:
In a mixture, the chemical present in the greatest amount is called a solvent, while the other components are called solutes. Then, the molarity or molar concentration is the number of moles of solute per liter of solution.
In other words, molarity is the number of moles of solute that are dissolved in a given volume.
The Molarity of a solution is determined by:
Molarity is expressed in units ().
Then you must know the number of moles of Cu(NO₂)₂. For that it is necessary to know the molar mass. Being:
the molar mass of Cu(NO₂)₂ is:
Cu(NO₂)₂= 63.54 g/mol + 2*(14 g/mol + 2* 16 g/mol)= 155.54 g/mol
Now the following rule of three applies: if 155.54 g are in 1 mole of the compound, 225 g in how many moles are they?
moles= 1.45
So you know:
Replacing in the definition of molarity:
Molarity= 0.56
<u><em>The molarity is 0.56</em></u><u><em></em></u>
Answer:
Therefore = -1835 KJ
Explanation:
Enthalpy is denoted by H.
Enthalpy: Total heat change in a chemical reaction is called enthalpy.
The change of entalpy of a reaction is denoted by
Hass's Law:The change in enthalpy of any process can be determined by calculating the sum of change in enthalpy of each of the steps involved in the process.
g= gas
S= solid
P₄(g)+10Cl₂(g)→ 4Cl₅(s) =?
PCl₅(s)→ PCl₃(g)+Cl₂(g) .......(1) = +157KJ
P₄(g)+6Cl₂(g)→ 4PCl₃(g).............(2) = -1207 KJ
If we flip a reaction the value of enthalpy will be change positive to negative or nagative to positive but the numerical value will be remain same.
We need rearrange the equation (1) because in the required equation Cl₂ is on the left side. So we flip the first equation.
PCl₃(g)+Cl₂(g)→PCl₅(s)......(3) = -157KJ
Multiplying 4 with equation (3)
4 PCl₃(g)+4Cl₂(g)→4PCl₅(s)......(4) =4×( -157)KJ= -628 KJ
Adding equation (2) and (4) we get
P₄(g)+6Cl₂(g)+4 PCl₃(g)+4Cl₂(g)→4PCl₃(g)+4PCl₅(s) =( -1207-628)KJ
⇒P₄(g)+10Cl₂(g)→4PCl₃(g)-4PCl₃(g)+4PCl₅(s) = - 1835KJ
⇒P₄(g)+10Cl₂(g)→ 4Cl₅(s) = -1835 KJ
Therefore = -1835 KJ