Stoichiometry time! Remember to look at the equation for your molar ratios in other problems.
31.75 g Cu | 1 mol Cu | 2 mol Ag | 107.9 g Ag 6851.65
⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻ → ⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻ = 107.9 g Ag
∅ | 63.5 g Cu | 1 mol Cu | 1 mol Ag 63.5
There's also a shorter way to do this: Notice the molar ratio from Cu to Ag, which is 1:2. When you plug in 31.75 into your molar mass for Cu, it equals 1/2 mol. That also means that you have 1 mol Ag because of the ratio, qhich you can then plug into your molar mass, getting 107.9 as well.
Answer is: formula of the complex is [Cr(NH₃)₂(SCN)₄<span>]</span>⁻<span>.
This complex has negative charge (-1) because chromium (central atom or metal) has oxidation number +3, first ligand ammonia has neutral charge and second ligand thiocyanate has negative oxidation number -1:
+3 + 2</span>·0 + 4·(-1) = -1.