Answer:
Balanced reaction: 
S is oxidized and N is reduced.
is the oxidizing agent and ZnS is the reducing agent.
Explanation:
Reaction: 
Oxidation: 
Balance charge:
...............(1)
Reduction: 
Balance H and O in acidic medium : 
Balance charge:
...............(2)
[
Equation-(1)] + [
Equation-(2)]:

Oxidation number of S increases from (-2) to (0) for the conversion of ZnS to S. Therefore S is oxidized.
Oxidation number of N decreases from (+5) to (+2) for the conversion of
to NO. Therefore N is reduced.
consumes electron from ZnS. Therefore
is the oxidizing agent and ZnS is the reducing agent.
<u>Answer:</u> The partial pressure of carbon dioxide at equilibrium is 0.0056 atm
<u>Explanation:</u>
The given chemical equation follows:

<u>Initial:</u> 4.00
<u>At eqllm:</u> 4.00-2x x x
The expression of
for above reaction follows:

The partial pressure of pure solids and liquids are taken as 1 in the equilibrium constant expression.
We are given:

Putting values in above expression, we get:

Neglecting the value of x = 718.28 because equilibrium pressure cannot be greater than initial pressure
Partial pressure of
= 0.0056 atm
Hence, the partial pressure of carbon dioxide at equilibrium is 0.0056 atm
8 electrons makes a full shell in an atom