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Answer:
See explanation
Explanation:
The reaction equation is;
C3H8 (g) + 5O2(g) -------> 4H2O(g) + 3CO2(g)
From the formula;
Total enthalpy of reactants = (ΔHf of Reactant 1 x Coefficient) + (ΔHf of Reactant 2 x Coefficient)
Total enthalpy of products= (ΔHf of Product 1 x Coefficient) + (ΔHf of Product 2 x Coefficient)
Hence;
Total enthalpy of reactants =[(-103.85 * 1) + (0 * 5)] = -103.85 + 0 = -103.85 KJ/mol
Total enthalpy of products= [(-393.51 * 4) +(-241.82 * 3)] = (-1574.04) + (-483.64) = -2057.68 KJ/mol
C ........................
Part A
75.0 mL of 0.10 M HF; 55.0 mL of 0.15 M NaF
This combination will form a buffer.
Explanation
Here, weak acid HF and its conjugate base F- is available in the solution
Part B
150.0 mL of 0.10 M HF; 135.0 mL of 0.175 M HCl
This combination cannot form a buffer.
Explanation
Here, moles of HF = 0.15 x 0.1 = 0.015 moles
Moles of HCl = 0.135 x 0.175 = 0.023
Since HCl is a strong acid and the number of HCl is higher than HF. This prevents the dissociation of HF and the conjugate base F- will not be available in the solution
Part C
165.0 mL of 0.10 M HF; 135.0 mL of 0.050 M KOH
This combination will form a buffer.
Explanation
Moles of HF = 0.165 x 0.1 = 0.0165 moles
Moles of KOH = 0.135 x 0.05 = 0.00675 moles
Moles of KOH is not sufficient for the complete neutralization of HF. Thus weak acid HF and its conjugate base F- is available in the solution and form a buffer
Part D
125.0 mL of 0.15 M CH3NH2; 120.0 mL of 0.25 M CH3NH3Cl
This combination will form a buffer
Explanation
Here, weak acid CH3NH3+ and its conjugate base CH3NH2 is available in the solution and form a buffer
Part E
105.0 mL of 0.15 M CH3NH2; 95.0 mL of 0.10 M HCl
This combination will form a buffer
Explanation
Moles of CH3NH2 = 0.105 x 0.15 = 0.01575 moles
Moles of HCl = 0.095 x 0.1 = 0.0095 moles
Thus the HCl completely reacts with CH3NH2 and converts a part of the CH3NH2 to CH3NH3+. This results weak acid CH3NH3+ and its conjugate base CH3NH2 is in the solution and form a buffer
