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3 years ago

What is the relationship between the atomic numbers and ionic radii of the elements in the group 7a

Chemistry

1 answer:

kvv77 [185]3 years ago

7 0

Answer:

The ionic radii increase as the atomic numbers increase.

Explanation:

As we go down a Group, we are adding one more electron shell to the ion.

Each successive shell is bigger than the one before it, so the ionic radius should increase with increasing atomic number.

Here is a table of the ionic radii of the X⁻ ions.

Element Z r/pm

F 9 133

Cl 17 181

Br 35 196

I 53 220

At 85 227

However, the relation between r and Z is not linear (see graph).

All we can say is the ionic radius increases as the atomic number increases.

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What type of chemical bond is hydrogen?

oksian1 [2.3K]

Hydrogen is a covalent bond. (A bond where one or more pairs of electrons are shared by two atoms)

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2 years ago

Part a use these data to calculate the heat of hydrogenation of buta-1,3-diene to butane. c4h6(g)+2h2(g)→c4h10(g)

Reptile [31]

Answer: The heat of hydrogenation of the reaction is coming out to be 234.2 kJ.

Explanation:

Enthalpy change is defined as the difference in enthalpies of all the product and the reactants each multiplied with their respective number of moles. It is represented as $\Delta H$

The equation used to calculate enthalpy change is of a reaction is:

$\Delta H_{rxn}=\sum [n\times \Delta H_{(product)}]-\sum [n\times \Delta H_{(reactant)}]$

For the given chemical reaction:

$C_4H_6(g)+2H_2(g)\rightarrow C_4H_{10}(g)$

The equation for the enthalpy change of the above reaction is:

$\Delta H_{rxn}=[(1\times \Delta H_{(C_4H_{10})})]-[(1\times \Delta H_{(C_4H_6)})+(2\times \Delta H_{(H_2)})]$

We are given:

$\Delta H_{(C_4H_{10})}=-2877.6kJ/mol\\\Delta H_{(C_4H_6)}=-2540.2kJ/mol\\\Delta H_{(H_2)}=-285.8kJ/mol$

Putting values in above equation, we get:

$\Delta H_{rxn}=[(1\times (-2877.6))]-[(1\times (-2540.2))+(2\times (-285.8))]\\\\\Delta H_{rxn}=234.2J$

Hence, the heat of hydrogenation of the reaction is coming out to be 234.2 kJ.

4 0

3 years ago

NaOH+HCl->............

Oxana [17]

Answer:

NaCl+H20

Explanation:

It is a neutralisation reaction in which NaOH is a base and HCl is an acid. On reaction it forms salt and water.

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3 0

2 years ago

Read 2 more answers

describe an example of how humans used selective breeding in plants,and explain how that has benefited us

Crank

The plants give out oxygen so for us humans will live

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3 years ago

A compound is 42.9% C, 2.4% H, 16.7% N, and 38.1% O, by mass. Addition of 6.45 g of this compound to 50.0 mL benzene, lowers the

Romashka [77]

This is an incomplete question, here is a complete question.

A compound is 42.9% C, 2.4% H, 16.7% N and 38.1% O by mass. Addition of 6.45 g of this compound to 50.0 mL benzene, C₆H₆ (d= 0.879 g/mL; Kf= 5.12 degrees Celsius/m), lowers the freezing point from 5.53 to 1.37 degrees Celsius. What is the molecular formula of this compound?

Answer : The molecular of the compound is, $C_6H_4N_2O_4$

Explanation :

First we have to calculate the mass of benzene.

$\text{Mass of benzene}=\text{Density of benzene}\times \text{Volume of benzene}$

$\text{Mass of benzene}=0.879g/mL\times 50.0mL=43.95g$

Now we have to calculate the molar mass of unknown compound.

Given:

Mass of unknown compound (solute) = 6.45 g

Mass of benzene (solvent) = 43.95 g = 0.04395 kg

Formula used :

$\Delta T_f=K_f\times m\\\\\Delta T_f=K_f\times\frac{\text{Mass of unknown compound}}{\text{Molar mass of unknown compound}\times \text{Mass of benzene in Kg}}$

where,

$\Delta T_f$ = change in freezing point = $5.53-1.37=4.16^oC$

$\Delta T_s$ = freezing point of solution

$\Delta T^o$ = freezing point of benzene

Molal-freezing-point-depression constant $(K_f)$ for benzene = $5.12^oC/m$

m = molality

Now put all the given values in this formula, we get

$4.16^oC=(5.12^oC/m)\times \frac{6.45g}{\text{Molar mass of unknown compound}\times 0.04395kg}$

$\text{Molar mass of unknown compound}=180.6g/mol$

If percentage are given then we are taking total mass is 100 grams.

So, the mass of each element is equal to the percentage given.

Mass of C = 42.9 g

Mass of H = 2.4 g

Mass of N = 16.7 g

Mass of O = 38.1 g

Molar mass of C = 12 g/mole

Molar mass of H = 1 g/mole

Molar mass of N = 14 g/mole

Molar mass of O = 16 g/mole

Step 1 : convert given masses into moles.

Moles of C = $\frac{\text{ given mass of C}}{\text{ molar mass of C}}= \frac{42.9g}{12g/mole}=3.575moles$

Moles of H = $\frac{\text{ given mass of H}}{\text{ molar mass of H}}= \frac{2.4g}{1g/mole}=2.4moles$

Moles of N = $\frac{\text{ given mass of N}}{\text{ molar mass of N}}= \frac{16.7g}{14g/mole}=1.193moles$

Moles of O = $\frac{\text{ given mass of O}}{\text{ molar mass of O}}= \frac{38.1g}{16g/mole}=2.381moles$

Step 2 : For the mole ratio, divide each value of moles by the smallest number of moles calculated.

For C = $\frac{3.575}{1.193}=2.99\approx 3$

For H = $\frac{2.4}{1.193}=2.01\approx 2$

For N = $\frac{1.193}{1.193}=1$

For O = $\frac{2.381}{1.193}=1.99\approx 2$

The ratio of C : H : N : O = 3 : 2 : 1 : 2

The mole ratio of the element is represented by subscripts in empirical formula.

The Empirical formula = $C_3H_2N_1O_2$

The empirical formula weight = 3(12) + 2(1) + 1(14) + 2(16) = 84 gram/eq

Now we have to calculate the molecular formula of the compound.

Formula used :

$n=\frac{\text{Molecular formula}}{\text{Empirical formula weight}}$

$n=\frac{180.6}{84}=2$

Molecular formula = $(C_3H_2N_1O_2)_n=(C_3H_2N_1O_2)_2=C_6H_4N_2O_4$

Therefore, the molecular of the compound is, $C_6H_4N_2O_4$

3 0

3 years ago