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mr_godi [17]
3 years ago
7

If the K a of a monoprotic weak acid is 1.0 × 10 − 6 , what is the [ H + ] of a 0.22 M solution of this acid?

Chemistry
1 answer:
prisoha [69]3 years ago
3 0

<u>Answer:</u> The concentration of hydrogen ions is 4.7\times 10^{-4}M

<u>Explanation:</u>

We are given:

Concentration of acid = 0.22 M

The chemical equation for the dissociation of monoprotic weak acid follows:

                       HA\rightleftharpoons H^++A^-

<u>Initial:</u>             0.22

<u>At eqllm:</u>       0.22-x    x     x

The expression of K_a for the above equation follows:

K_a=\frac{[H^+][A^-]}{[HA]}

We are given:

K_a=1.0\times 10^{-6}

Putting values in above equation, we get:

1.0\times 10^{-6}=\frac{x\times x}{(0.22-x)}\\\\x=-0.00047,0.00047

Neglecting the negative value of 'x', because concentration cannot be negative

So, equilibrium concentration of hydrogen ions = x = 0.00047 M = 4.7\times 10^{-4}M

Hence, the concentration of hydrogen ions is 4.7\times 10^{-4}M

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\begin{gathered} \Delta H=1154.2kJ+(-828.0kJ)+(-597.4kJ) \\ \Delta H=1154.2kJ-828.0kJ-597.4kJ \\ \Delta H=-271.2kJ \end{gathered}

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\Delta H_m=-\frac{271.2kJ}{1mol}=-271.2kJ\/mol

So, the molar enthalpy of formation given the data is -271.2 kJ/mol.

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