Answer:
-The other substances that give a positive test with AgNO3 are other chlorides present, iodides and bromide.
-It is reasonable to exclude iodides and bromides but it is not reasonable to exclude other chlorides
Explanation:
In the qualitative determination of halogen ions, silver nitrate solution(AgNO3) is usually used. Now, various halide ions will give various colours of precipitate when mixed with with silver nitrate. For example, chlorides(Cl-) normally yield a white precipitate, bromides(Br-) normally yield a cream precipitate while iodides (I-) normally yield a yellow precipitate. Thus, all these ions or some of them may be present in the system.
With that being said, if other chlorides are present, they will also yield a white precipitate just like KCl leading to a false positive test for KCl. However, since other halogen ions yield precipitates of different colours, they don't lead to a false test for KCl. Thus, we can exclude other halides from the tendency to give us a false positive test for KCl but not other chlorides.
Answer:
378mL
Explanation:
The following data were obtained from the question:
Pressure (P) = 99.19 kPa
Temperature (T) = 28°C
Number of mole (n) = 0.015 mole
Volume (V) =...?
Next, we shall convert the pressure and temperature to appropriate units. This is illustrated below:
For Pressure:
101.325 KPa = 1 atm
Therefore, 99.19 kPa = 99.19/101.325 = 0.98 atm
For Temperature:
T(K) = T(°C) + 273
T(°C) = 28°C
T(K) = 28°C + 273 = 301K.
Next we shall determine the volume of N2. The volume of N2 can be obtained by using the ideal gas equation as shown below:
PV = nRT
Pressure (P) = 0.98 atm
Temperature (T) = 301K
Number of mole (n) = 0.015 mole
Gas constant (R) = 0.0821atm.L/Kmol.
Volume (V) =...?
0.98 x V = 0.015 x 0.0821 x 301
Divide both side by 0.98
V = (0.015 x 0.0821 x 301) /0.98
V = 0.378 L
Finally, we shall convert 0.378 L to millilitres (mL). This is illustrated below:
1L = 1000mL
Therefore, 0.378L = 0.378 x 1000 = 378mL
Therefore, the volume of N2 collected is 378mL
Answer:
0.0277 M.
Explanation:
The integral rate law of a first order reaction:
<em>Kt = ln ([A₀]/[A]),</em>
where, k is the rate constant of the reaction <em>(k = 3.36 × 10⁻⁵ s⁻¹)</em>,
t is the time of the reaction <em>(t = 235.0 min = 14100 s)</em>,
[A₀] is the initial concentration of cyclopropane <em>([A₀] = 0.0445 M)</em>
<em>∵ Kt = ln ([A₀]/[A]),</em>
∴ (3.36 × 10⁻⁵ s⁻¹)(14100 s) = ln (0.0445 M)/[A]
Taking the exponential of both sides:
1.6 = (0.0445 M)/[A]
<em>∴ [A] = (0.0445 M)/1.6 = 0.0277 M.</em>
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