According to markovnikov's rule of the electrophilic addition to an alkene, the electrophile, usually a proton, is more likely to add to the less-substituted carbon in a double bond.
With additional substituents present in this configuration, the intermediate carbocation is stabilised by being located on the more-substituted carbon.
The nucleophile will then end up in a double bond on the more-substituted carbon in a reaction that follows Markovnikov's rule.The outcome of some addition reactions is described by Markovnikov's rule or Markownikoff's rule in organic chemistry. Vladimir Markovnikov, a Russian scientist, created the rule in 1870.
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The electrons closer to the nucleus would have more energy than the electrons farther away from the nucleus.
