The first one is exothermic because energy is a reactant, the second formula is endothermic
To answer this problem, we must make assumptions for simplicity. The first assumption is that, the system only consist of these 3 gases. The second assumption is that, these gases behave ideally. Thus, from Dalton's Law of Partial Pressure, the total pressure is simply the sum of their individual partial pressures.
Total pressure = 2.5 + 0.8 + 3.4 = <em>6.7 atm</em>
Answer : The mass of sulfuric acid needed is 
.
Solution : Given,
pH = 8.94
Volume of solution = 380 ml = 
Molar mass of sulfuric acid = 98.079 g/mole
As we know,
![pOH=-log[OH^-]](https://tex.z-dn.net/?f=pOH%3D-log%5BOH%5E-%5D)
![5.06=-log[OH^-]](https://tex.z-dn.net/?f=5.06%3D-log%5BOH%5E-%5D)
![[OH^-]=0.00000871=8.71\times 10^{-6}mole/L](https://tex.z-dn.net/?f=%5BOH%5E-%5D%3D0.00000871%3D8.71%5Ctimes%2010%5E%7B-6%7Dmole%2FL)
Now we have to calculate the moles of 
.
Formula used : 
![\text{ Moles of }[OH^-]=\text{ Concentration of }[OH^-]\times Volume\\\text{ Moles of }[OH^-]=(8.71\times 10^{-6}mole/L)\times (380\times 10^{-3}L)=3309.8\times 10^{-9}moles](https://tex.z-dn.net/?f=%5Ctext%7B%20Moles%20of%20%7D%5BOH%5E-%5D%3D%5Ctext%7B%20Concentration%20of%20%7D%5BOH%5E-%5D%5Ctimes%20Volume%5C%5C%5Ctext%7B%20Moles%20of%20%7D%5BOH%5E-%5D%3D%288.71%5Ctimes%2010%5E%7B-6%7Dmole%2FL%29%5Ctimes%20%28380%5Ctimes%2010%5E%7B-3%7DL%29%3D3309.8%5Ctimes%2010%5E%7B-9%7Dmoles)
For neutralization, equal number of moles of 
ions will neutralize same number of ions.
![\text{ Moles of }[OH^-]=\text{ Moles of }[H^+]=3309.8\times 10^{-9}moles](https://tex.z-dn.net/?f=%5Ctext%7B%20Moles%20of%20%7D%5BOH%5E-%5D%3D%5Ctext%7B%20Moles%20of%20%7D%5BH%5E%2B%5D%3D3309.8%5Ctimes%2010%5E%7B-9%7Dmoles)
As, 
From this reaction, we conclude that
2 moles of ion is given by the 1 mole of 
moles of ion is given by 
moles of
Now we have to calculate the mass of sulfuric acid.
Mass of sulfuric acid = Moles of × Molar mass of sulfuric acid
Mass of sulfuric acid = 
Therefore, the mass of sulfuric acid needed is .
Answer:
The nucleus represents a major evolutionary transition. As a consequence of separating translation from transcription many new functions arose, which likely contributed to the remarkable success of eukaryotic cells. Here we will consider what has recently emerged on the evolutionary histories of several key aspects of nuclear biology; the nuclear pore complex, the lamina, centrosomes and evidence for prokaryotic origins of relevant players.
