Answer:
pH = 2.03
Explanation:
The pH can be calculated using the following equation:
(1)
The concentration of H₃O⁺ is calculated using the dissociation constant of the next reaction:
CH₃COOH + H₂O ⇄ CH₃COO⁻ + H₃O⁺
1.00 M
Solving the above equation for H₃O⁺, we have:
(2)
The dissociation constant is equal to:
Now, by solving the equation of the solubility product for Herbigon, we can find [CH₃COO⁻]:
CH₃COOX ⇄ CH₃COO⁻ + X⁺
5.00x10⁻³ M
By entering the values of [CH₃COO⁻] and Ka, into equation (2) we can calculate [H₃O⁺]:
Hence, the pH is:
Therefore, the pH must be 2.03 to yield a solution in which the concentration of X⁺ is 5.00x10⁻³M.
I hope it helps you!
Answer:
One can determine the specific heat of the metal through using the clarimeter, water, thermometer and using heat equations.
Explanation:
You can learn about heat effects and calorimetery through a simple experiment by boiling water and heating up the metal in it. Then, pour it into your calorimeter and the heat will flow from the metal to the water. The two equlibria will meet: the metal will loose heat into its surroundings (the water) and teh water will absorb the heat. The heat flow for the water is the same as it is for the metal, the only difference being is the negative sign indicating the loss of the heat of the metal.
In terms of theromdynamics, we can deteremine the heat flow for the metal becasue it would be equal to the mangnitued but opposite in direction. Thus, we can say that the specific heat of water qH2O = -qmetal.
Answer:
-4.59°C
Explanation:
Let's see the formula for freezing point depression.
ΔT = Kf . m . i
ΔT = Freezing T° of pure solvent - Freezing T° of solution
Kf = Freezing constant. For water if 1.86°C/m
m = molality (moles of solute in 1kg of solvent)
i = Van't Hoff factor.
0°C - Freezing T° of solution = 1.86°C /m . 1.30m . 1.9
Freezing T° of solution = - (1.86°C /m . 1.30m . 1.9)
Freezing T° of solution = - (1.86°C/m . 1.30m . 1.9) → -4.59°C
NaCl → Na⁺ + Cl⁻
Given:
0.060 mol of NiC2O4
Ksp = 4 x 10⁻¹⁰
1.0 L of solution
Kf of Ni(NH3)6 2⁺ = 1.2 x 10⁹
<span>NiC2O4 + 6NH3 ⇋ Ni(NH3)6 2+ + 2O4 2- </span>
<span>NiC2O4 ⇋ Ni 2+ + C2O4 2- ...Ksp </span>
<span>Ni2+ + 6NH3 ⇋ Ni(NH3)6 2+...Kf </span>
Ksp * Kf = (4 x 10⁻¹⁰) * (1.2 x 10⁹) = 0.48
K = 0.48 = [Ni(NH3)6 2+][C2O4 2-] / [NH3]⁶<span>
</span>0.48 = (0.060)² / [NH3]⁶<span> ... (dissolved C2O4 2- = 0.060M)
</span><span>[NH3]</span>⁶<span> = (0.060)</span>²<span> / 0.48 = </span>0.0036 / 0.48 = 0.0075
NH3 = ⁶√0.0075
NH3 = 0.44 M