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3 years ago

HELP!!!!!!!!!!! *What are some of the safety concerns for Barium sulfate & Barium Sulfide? Explain

Chemistry

1 answer:

Alex3 years ago

3 0

BaSO₄ is relatively harmless, but BaS is highly toxic.

BaSO₄ is quite insoluble (240 µg/100 mL). It is a mild irritant in cases of skin contact and inhalation. However, it is safe enough that health professionals ask patients to drink a suspension of BaSO₄. The Ba is opaque to X-rays, so it makes the stomach and intestines more visible to radiographers.

BaS is soluble (7.7 g/100 mL). It reacts slowly with water and more rapidly in the acid conditions of the stomach to release H₂S.

BaS + 2HCl ⟶ BaCl₂ + H₂S

An H₂S concentration of 60 mg/100 mL can be fatal within 30 min.

Don’t eat barium sulfide!

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3 years ago

. The kidneys are _______________ to the liver.

m_a_m_a [10]

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3 years ago

Which of the following reactions could be an elementary reaction? 2 NO2(g) + F2(g) → 2NO2F(g) Rate = k[NO2][F2] H2(g) + Br2(g) →

podryga [215]

Answer: The correct answer is $NO(g)+O_2(g)\rightarrow NO_2(g)+O(g);Rate=k[NO][O_2]$

Explanation:

Molecularity of the reaction is defined as the number of atoms, ions or molecules that must colloid with one another simultaneously so as to result into a chemical reaction.

Order of the reaction is defined as the sum of the concentration of terms on which the rate of the reaction actually depends. It is the sum of the exponents of the molar concentration in the rate law expression.

Elementary reactions are defined as the reactions for which the order of the reaction is same as its molecularity and order with respect to each reactant is equal to its stoichiometric coefficient as represented in the balanced chemical reaction.

For the given reactions:

Equation 1: $2NO_2(g)+F_2(g)\rightarrow 2NO_2F(g);Rate=k[NO_2][F_2]$

Molecularity of the reaction = 2 + 1 = 3

Order of the reaction = 1 + 1 = 2

This is not considered as an elementary reaction.

Equation 2: $H_2(g)+Br_2(g)\rightarrow 2HBr(g);Rate=k[H_2][Br_2]^{1/2}$

Molecularity of the reaction = 1 + 1 = 2

Order of the reaction = $1+\frac{1}{2}=\frac{3}{2}$

This is not considered as an elementary reaction.

Equation 3: $NO(g)+O_2(g)\rightarrow NO_2(g)+O(g);Rate=k[NO][O_2]$

Molecularity of the reaction = 1 + 1 = 2

Order of the reaction = 1 + 1 = 2

This is considered as an elementary reaction.

Equation 4: $NO_2(g)+CO(g)\rightarrow NO(g)+CO_2(g);Rate=k[NO_2]^2$

Molecularity of the reaction = 1 + 1 = 2

Order of the reaction = 2 + 0 = 2

In this equation, the order with respect to each reactant is not equal to its stoichiometric coefficient which is represented in the balanced chemical reaction. Hence, this is not considered as an elementary reaction.

Hence, the correct answer is $NO(g)+O_2(g)\rightarrow NO_2(g)+O(g);Rate=k[NO][O_2]$

3 0

3 years ago

The vapor pressure of a substance is measured over a range of temperatures. A plot of the natural log of the vapor pressure vers

Gala2k [10]

Answer:

28.7664 kJ /mol

Explanation:

The expression for Clausius-Clapeyron Equation is shown below as:

$\ln P = \dfrac{-\Delta{H_{vap}}}{RT} + c$

Where,

P is the vapor pressure

ΔHvap is the Enthalpy of Vaporization

R is the gas constant (8.314×10⁻³ kJ /mol K)

c is the constant.

The graph of ln P and 1/T gives a slope of - ΔHvap/ R and intercept of c.

Given :

Slope = -3.46×10³ K

So,

- ΔHvap/ R = -3.46×10³ K

ΔHvap = 3.46×10³ K × 8.314×10⁻³ kJ /mol K = 28.7664 kJ /mol

6 0

3 years ago