During the electrolysis of the molten lithium chloride, the Lithium ions (Li⁺) at the cathode undergoes reduction, and the electron configuration of lithium becomes 1s²2s¹.
<h3>What is electrolysis?</h3>
Electrolysis can be described as the process in which the electric current is passed through the chemical compound to break them. In this process, the atoms and ions are interchanged by the addition or removal of electrons.
The ions are allowed to move freely in this process. When an ionic compound is melted or dissolved in water then ions are produced which can move freely.
During the electrolysis of molten lithium chloride, the lithium ions reach the cathode and accept the electrons while chloride ions reach at anode and loss electrons to become chlorine gas.
At anode : 2 Cl⁻ → Cl₂ + 2e⁻
At cathode: 2 Li⁺ + 2e⁻ → Li
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The temperature of vinegar does increase the rate of reaction according to the collision theory.
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Answers and Explanation:
a)- The chemical equation for the corresponden equilibrium of Ka1 is:
2. HNO2(aq)⇌H+(aq)+NO−2
Because Ka1 correspond to a dissociation equilibrium. Nitrous acid (HNO₂) losses a proton (H⁺) and gives the monovalent anion NO₂⁻.
b)- The relation between Ka and the free energy change (ΔG) is given by the following equation:
ΔG= ΔGº + RT ln Q
Where T is the temperature (T= 25ºc= 298 K) and R is the gases constant (8.314 J/K.mol)
At the equilibrium: ΔG=0 and Q= Ka. So, we can calculate ΔGº by introducing the value of Ka:
⇒ 0 = ΔGº + RT ln Ka
ΔGº= - RT ln Ka
ΔGº= -8.314 J/K.mol x 298 K x ln (4.5 10⁻⁴)
ΔGº= 19092.8 J/mol
c)- According to the previous demonstation, at equilibrium ΔG= 0.
d)- In a non-equilibrium condition, we have Q which is calculated with the concentrations of products and reactions in a non equilibrium state:
ΔG= ΔGº + RT ln Q
Q= ((H⁺) (NO₂⁻))/(HNO₂)
Q= ( (5.9 10⁻² M) x (6.7 10⁻⁴ M) ) / (0.21 M)
Q= 1.88 10⁻⁴
We know that ΔGº= 19092.8 J/mol, so:
ΔG= ΔGº + RT ln Q
ΔG= 19092.8 J/mol + (8.314 J/K.mol x 298 K x ln (1.88 10⁻⁴)
ΔG= -2162.4 J/mol
Notice that ΔG<0, so the process is spontaneous in that direction.
Ribosomes hope this helps if not oh well
In all atoms, the number of protons and the number of electrons is always the same. The number of neutrons is very roughly the same as the number of protons, but sometimes it's rather more. The number of protons in an atom is called the atomic number and it tells you what type of atom you have.
