For the second one it is physical
Scientific questions and hypotheses come up frequently while one is engaged in investigating a scientific phenomenon such as natural geological phenomena as may occur in geological mapping in the field. For example, there may be a question does this canyon or deeply incised valley which is quite straight follow a weakness in the earth's crust like a major fault or the direction of bedding in well bedded sedimentary rocks. In a particular topographic area, some hypotheses which may be developed is that valleys follow geological structure whereas ridges follow resistant rocks like quartzites or quartz sandstones or in the ocean, points or capes may represent resistant quartz sandstones and bays may represent weak soft shales recessively weathering
I believe the correct answer is the first option. To increase the molar concentration of the product N2O4, you should increase the pressure of the system. You cannot determine the effect of changing the temperature since we cannot tell whether it is an endothermic or an exothermic reaction. Also, decreasing the number of NO2 would not increase the product rather it would shift the equilibrium to the left forming more reactants. The only parameter we can change would be the pressure. And, since NO2 takes up more space than the product increasing the pressure would allow the reactant to collide more forming the product.
(1) IS THE BALANCED EQUATION AND REACTANT-> MG AND N2 AND PRODUCT ->MGN2.
(2) IS NOT BALANCED AND REACTANT->CF4 AND BR AND PRODUCT IS CBR4 AND F2
A, O2 has to be a reactant for combustion to burn