Answer: The molecular mass of this compound is 131 g/mol
Explanation:
Depression in freezing point:
where,
= depression in freezing point =
= freezing point constant = 
m = molality
i = Van't Hoff factor = 1 (for non-electrolyte)
= mass of solute = 0.49 g
= mass of solvent (cyclohexane) = 20.00 g
= molar mass of solute = ?
Now put all the given values in the above formula, we get:
Therefore, the molar mass of solute is 131 g/mol
<u>Answer:</u> The correct statement is low temperature only, because entropy decreases during freezing.
<u>Explanation:</u>
The relationship between Gibb's free energy, enthalpy, entropy and temperature is given by the equation:

Where,
= change in Gibb's free energy
= change in enthalpy
T = temperature
= change in entropy
It is given that freezing of methane is taking place, which means that entropy is decreasing and
is becoming negative. It is also given that the reaction is an exothermic reaction, this means that the
is also negative.
For a reaction to be spontaneous,
must be negative.
![-ve=-ve-[T(-ve)]\\\\-ve=-ve+T](https://tex.z-dn.net/?f=-ve%3D-ve-%5BT%28-ve%29%5D%5C%5C%5C%5C-ve%3D-ve%2BT)
From above equations, it is visible that
will be negative only when the temperature will be low.
Hence, the correct statement is low temperature only, because entropy decreases during freezing.
Answer:
-65.897°C.
Explanation:
- Adding solute to water causes depression of the boiling point.
- The depression in freezing point (ΔTf) can be calculated using the relation: <em>ΔTf = Kf.m,</em>
where, ΔTf is the depression in freezing point of chloroform solution.
Kf is the molal depression constant of chloroform (Kf = 4.70°C.kg/mol).
m is the molality of the solution (m = 0.51 m).
∴ ΔTf = Kf.m = (4.70°C.kg/mol)(0.51 m) = 2.397°C.
∴ The freezing point of the solution = (freezing point of chloroform) - ΔTf = (-63.5°C) - (2.397°C) = -65.897°C.