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jonny [76]
3 years ago
9

The base-dissociation constant, kb, for pyridine, c5h5n, is 1.4x10-9 the acid-dissociation constant, ka, for the pyridinium ion,

(pyridine's conjugate acid, is __________.
Chemistry
1 answer:
sp2606 [1]3 years ago
5 0
We are given the base dissociation constant, Kb, for Pyridine (C5H5N) which is 1.4x10^-9. The acid dissociation constant, Ka for the Pyridium ion or the conjugate acid of Pyridine is to be determined. We know from our chemistry classes that:

Kw = Kb * Ka

where Kw is always equal to 1x10^-14

so, to solve for Ka of Pyridium ion, substitute Kb to the equation together with Kw and solve for Ka:

1x10^-14 = 1.4x10^-9 * Ka
solve for Ka

Ka = 7.14x10^-6 

Therefore, the acid dissociation constant of Pyridinium ion is 7.14x10^-6.
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The partial stress of H2 is 737.47 mmHg Let's observe the Ideal Gas Law to find out the whole mols.

We count on that the closed vessel has 1L of volume

  • P.V=n.R.T
  • We must convert mmHg to atm. 760 mmHg.
  • 1 atm
  • 755 mmHg (755/760) = 0.993 atm
  • 0.993 m.1L=n.0.082 L.atm/mol.K .
  • 293 K(0.993 atm 1.1L)/(0.082mol.K /L.atm).
  • 293K = n
  • 0.0413mols = n

These are the whole moles. Now we are able to know the moles of water vapor, to discover the molar fraction of it.

  1. P.V=n.R.T
  2. 760 mmHg. 1 atm
  3. 17.5 mmHg (17.5 mmHg / 760 mmHg)=0.0230 atm
  4. 0.0230 m.1L=n.0.082 L.atm/mol.K.293 K(0.0230atm.1L)/(0.082mol.K/L.atm .293K)=n 9.58 × 10 ^ 4 mols = n.
  5. Molar fraction = mols )f gas/general mols.
  6. Molar fraction water vapor =9.58×10^ -four mols / 0.0413 mols
  7. Sum of molar fraction =1
  8. 1 - 9.58 × 10 ^ 4 × mols / 0.0413 ×mols = molar fraction H2
  9. 0.9767 = molar fraction H2
  10. H2 pressure / Total pressure =molar fraction H2
  11. H2 pressure / 55mmHg = =0.9767 0.9767 = h2 pressure =755 mmHg.
  12. 737,47 mmHg.
<h3>What is a mole fraction?</h3>

Mole fraction is a unit of concentration, described to be identical to the variety of moles of an issue divided through the whole variety of moles of a solution. Because it's miles a ratio, mole fraction is a unitless expression.

Thus it is clear that the partial pressure of H2 is 737,47 mmHg.

To learn  more about partial pressure refer to the link :

brainly.com/question/19813237

<h3 />

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3 years ago
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